Answer:
54 grams ammonium chloride and 40 grams sodium hydroxide
Explanation:
A buffer is a solution that contains either a weak acid and its salt or a weak base and its salt, the solution is resistant to changes in pH. This means that, a buffer is an aqueous solution of either a weak acid and its conjugate base or a weak base and its conjugate acid.
A Buffer is used to maintain a stable pH in a solution, buffers can neutralize small quantities of additional acid of base. For any buffer solution, there is always a working pH range and a set amount of acid or base that can be neutralized before the pH will change. The amount of acid or base that can be added to a buffer before changing its pH is called its buffer capacity.
A good buffer mixture is supposed to have about equal concentrations of its both components. It is a rule of thumb therefore, that a buffer solution has generally lost its usefulness when one component of the buffer pair is less than about 10% of the other component.
The implication of this is that the ammonium chloride and sodium hydroxide should be of approximately the same concentration. If the masses are dissolved as shown in the answer, then we will have 1molL-1 of each component of the buffer in accordance with the rule of thumb stated above.
Explanation:
Let us assume that total mass of the solution is 100 g. And, as it is given that acetic acid solution is 12% by mass which means that mass of acetic acid is 12 g and 88 g is the water.
Now, calculate the number of moles of acetic acid as its molar mass is 60 g/mol.
No. of moles = 
= 
= 0.2 mol
Molarity of acetic acid is calculated as follows.
Density = 
1 g/ml = 
volume = 100 ml
Hence, molarity = 
= 
= 2 mol/l
As reaction equation for the given reaction is as follows.
So, moles of NaOH = moles of acetic acid
Let us suppose that moles of NaOH are "x".
(as 1 L = 1000 ml)
x = 20 L
Thus, we can conclude that volume of NaOH required is 20 ml.
Answer:
The coordination sphere of a complex consists of <u><em>the central metal ion and the ligands bonded to it.</em></u>
Explanation:
The Coordination Compounds are sets of a central metal ion attached to a group of molecules or ions that surround it. They are also called metal complexes or simply complexes. Then they are compounds that have a central atom surrounded by a group of molecules or ions, the latter called ligands.
The central atom must have empty orbitals capable of accepting pairs of electrons, with the transition metals being the ones with the greatest tendency. Because of this, they can act as Lewis acids (electron pair acceptors). The ligands have unshared electron pairs, then acting as Lewis bases (electron pair donors).
When forming a complex, it is said that the ligands coordinate to the metal and the central metal and the ligands attached to it constitute the coordination sphere of the complex.
Finally, <u><em>the coordination sphere of a complex consists of the central metal ion and the ligands bonded to it.</em></u>
