1. diffusion is a physical process when there is random motion of molecules by which there is a net flow of matter from a region of high concentration to a region of low concentration.
2. Osmosis is the diffusion of water where molecules of water move passively (without energy) from high concentration to low concentration. eg: the way water rushes into a sponge.
3. Active transport moves particles from low to higher concentration. The difference between diffusion and active transport is diffusion does not require energy (eg: oxygen moving from the airways to the lungs - there is very little oxygen in the lungs but lots in the air). whereas active transport does require energy (eg: when plants take up nutrients from the soil. The soil does not have a large concentration of nutrients, but the plant does)
It is rinsed one last time with the solution to be measured because if there is water in the burret, then it could alter the results. Slightly, but it is still altering it.