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BARSIC [14]
3 years ago
11

A student prepares 150. mL of a 2.00 M Ba(OH)2 aqueous solution in lab. What mass of Ba(OH)2 is fully dissolved in the solution?

Chemistry
1 answer:
meriva3 years ago
3 0

Answer: 51.4g

Explanation:

Given that:

Amount of moles of Ba(OH)2 (n) = ?

Volume of Ba(OH)2 solution (v) = 150.0mL

[Convert 150.0mL to liters

If 1000 mL = 1L

150.0mL = 150.0/1000 = 0.150L]

Concentration of Ba(OH)2 solution (c) = 2.00M

Since concentration (c) is obtained by dividing the amount of solute dissolved by the volume of solvent, hence

c = n / v

make n the subject formula

n = c x v

n = 2.00M x 0.150L

n = 0.3 mole

Now given that,

Amount of moles of Ba(OH)2 (n) = 0.3

Mass of Ba(OH)2 in grams (m) = ?

For molar mass of Ba(OH)2, use the molar masses:

Barium, Ba = 137.3g;

Oxygen, O = 16g;

Hydrogen, H = 1g

Ba(OH)2 = 137.3g + [(16g + 1g) x 2]

= 137.3g + [17g x 2]

= 137.3g + 34g

= 171.3 g/mol

Since, amount of moles = mass in grams / molar mass

0.3 mole= m / 171.3g/mol

m = 0.3 mole x 171.3g/mol

m = 51.39g

[Round the 51.39g to the nearest tenth, so it becomes 51.4g]

Thus, the mass of Ba(OH)2 fully dissolved in the solution is 51.4 grams

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Explanation:

As per the Hess’s law of constant heat summation, the heat absorbed or evolved in a given chemical equation is the same whether the process occurs in one step or several steps.

Hence, according to this law the chemical equation can be treated as ordinary algebraic expression and can be added or subtracted to yield the required equation. This means that the enthalpy change of the overall reaction is the sum of the enthalpy changes of the intermediate reactions.

Sb + \frac{3}{2}Cl_2 \rightarrow SbCl_{3}    \Delta H^0_1 =  -314 kJ  ..........(1)

SbCl_{3} + Cl_2 \rightarrow SbCl_{5}    \Delta H^0_2 = -80kJ   ..............(2)

The final reaction is as follows:  

Sb + \frac{5}{2}Cl_{2} \rightarrow SbCl_{5}  \Delta H^0_3 = ?  .............(3)

Therefore, adding (1) and (2) we get the final equation (3) and value of \Delta H^{0}_{3} at 298 K will be as follows.

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