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vovangra [49]
3 years ago
10

The normal boiling point of a substance is defined to be the temperature at which the liquid phase of the substance is in equili

brium with the gas phase at 1 atm pressure. The normal boiling point of methanol is 80oC and ∆H vap = 38 kJ/mol. What is the ∆Scrap value
Chemistry
1 answer:
boyakko [2]3 years ago
5 0

Answer:

ΔSv = 0.1075 KJ/mol.K

Explanation:

Binary solution:

∴ a: solvent

∴ b: solute

in equilibrium:

  • μ*(g) = μ(l) = μ* +RTLnXa....chemical potential (μ)

⇒ Ln (1 - Xb) = ΔG/RT

∴ ΔG = ΔHv - TΔSv

⇒ Ln(1 -Xb) = ΔHv/RT - ΔSv/R

∴ Xb → 0:

⇒ Ln(1) = ΔHv/RT - ΔSv/R

∴ T = T*b....normal boiling point

⇒ 0 = ΔHv/RT*b - ΔSv/R

⇒ ΔSv = (R)(ΔHv/RT*b)

⇒ ΔSv = ΔHv/T*b

∴ T*b = 80°C ≅ 353 K

⇒ ΔSv = (38 KJ/mol)/(353 K)

⇒ ΔSv = 0.1075 KJ/mol.K

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The main criterion for sigma bond formation is that the two bonded atoms have valence orbitals with lobes that point directly at
nalin [4]

Answer:

The given statement - The main criterion for sigma bond formation is that the two bonded atoms have valence orbitals with lobes that point directly at each other along the line between the two nuclei , is <u>True.</u>

Explanation:

The above statement is correct , because the sigma bond is produced by the head on overlapping, the orbitals should all point in the same direction.

<u>SIGMA BONDS -</u> Sigma bonds (bonds) are the strongest type of covalent chemical bond in chemistry. They're made up of atomic orbitals that collide head-on. For diatomic molecules, sigma bonding is best characterized using the language and tools of symmetry groups.

Head-on overlapping of atomic orbitals produces sigma bonds. The concept of sigma bonding is expanded to include bonding interactions where a single lobe of one orbital overlaps with a single lobe of another. Propane, for example, is made up of ten sigma bonds, one for each of the two CC bonds and one for each of the eight CH bonds.

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2 years ago
55 L of a gas at 25oC has its temperature increased to 35oC. What is its new volume?
ladessa [460]

Answer:

Approximately 56.8 liters.

Assumption: this gas is an ideal gas, and this change in temperature is an isobaric process.

Explanation:

Assume that the gas here acts like an ideal gas. Assume that this process is isobaric (in other words, pressure on the gas stays the same.) By Charles's Law, the volume of an ideal gas is proportional to its absolute temperature when its pressure is constant. In other words

\displaystyle V_2 = V_1\cdot \frac{T_2}{T_1},

where

  • V_2 is the final volume,
  • V_1 is the initial volume,
  • T_2 is the final temperature in degrees Kelvins.
  • T_1 is the initial temperature in degrees Kelvins.

Convert the temperatures to degrees Kelvins:

T_1 = \rm 25^{\circ}C = (25 + 273.15)\; K = 298.15\; K.

T_2 = \rm 35^{\circ}C = (35 + 273.15)\; K = 308.15\; K.

Apply Charles's Law to find the new volume of this gas:

\displaystyle V_2 = V_1\cdot \frac{T_2}{T_1} = \rm 55\;L \times \frac{308.15\; K}{298.15\; K} = 56.8\; L.

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il63 [147K]

Answer:

Density

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Density is defined as the mass per unit volume. It is the ratio between the mass and the volume of a substance. It does not matter how large or small a sample of matter is, the same substance will always have the same density, because of this. The ratio between the mass and volume remains the same.

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