Answer:
Explanation has been given below.
Explanation:
- Chloroform has three polar C-Cl bonds. Methylene chloride has two polar C-Cl bonds. So it is expected that chloroform should be more polar and posses higher dipole moment than methylene chloride.
- Two factors are liable for the opposite trend observed in dipole moments of methylene chloride and chloroform.
- First one is the number of hyperconjugative hydrogen atoms present in a molecule. Hyperconjugation occurs with vacant d-orbital of Cl atom. Hyperconjugation amplifies charge separation in a molecule resulting higher dipole moment.
- Methylene chloride has two hyperconjugative hydrogen atoms and chloroform has one hyperconjugative hydrogen atom.Therefore methylene chloride should have higher charge separation as compared to chloroform.
- Second one is induction of opposite polarity in a C-Cl bond by another C-Cl bond in a molecule. Higher the opposite induction of polarity, lower the charge separation in a molecule and hence lower the dipole moment of a molecule.
- Chloroform has three C-Cl bonds and methylene chloride has two C-Cl bonds. Therefore opposite induction is higher for chloroform resulting it's lower dipole moment.
pH is the measure of the hydrogen ion concentration while pOH is of hydroxide ion concentration in the solution. The pH is 0.939 and pOH is 13.061 pOH.
pH is the concentration of the hydrogen ion released or gained by the species in the solution that depicts the acidity and basicity of the solution.
pOH is the concentration of the hydroxide ion in the solution and is dependent on the pH as an increase in pH decreases the pOH and vice versa.
Both HCl and HBr are strong acids and gets ionized 100 % in the solution. If we let 1 L of solution for the acids then the concentration of the hydrogen ion will be 0.100 M.
Since both completely dissociate we would just add the molarities of each of the H+ ions together and then calculate the PH and POH from that :
HCL(0.040M)----> H+(0.040M) +CL-(0.040M)
HBr(0.075M)----> H+(0.075M) +Br-(0.075M)
so 0.040M (H+ from HCL) + 0.075M (H+ from HBr) = 0.115M H+ in total.
pH is calculated as:
pH = -log[H+]
Substituting values in the equation:
log(0.115M)= 0.939 pH
pOH is calculated as:
14 - pH = pOH
Substituting values in the equation above:
14 - 0.939= 13.061 pOH
Therefore, pH is 0.939 and pOH is 13.061.
Learn more about pH and pOH here:
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Answer:
See Explanation Below
Explanation:
A) The rate law can only be on the reactant side and you can only determine it after you get the net ionic equation because of spectators cancelling out. So in this case the rate law is k=[CH3Br]^1 [OH-]^1. The powers are there because the rxn is first order.
B) Since the rxn is first order anything you do to it will be the exact same "counter rxn" per say so since you are decreasing the OH- by 5 the rate will decease by 5
C) The rate will increase by 4 since you are doubling both you have to multiply them both.
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