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algol [13]
4 years ago
13

Determine the concentration of the following dye standard made by a student who pipettes out 2.50 mL of a 0.250 M stock solution

and transfers it into a volumetric flask and dilutes the dye to a final volume of 100.0 mL with DI water.
Chemistry
1 answer:
Thepotemich [5.8K]4 years ago
7 0

Answer:

Concentration of dye in diluted solution is 0.00625 M

Explanation:

The given problem can be solved by using laws of dilution

According to laws of dilution-   C_{1}V_{1}=C_{2}V_{2}

where C_{1} and C_{2} are initial and final concentration respectively

          V_{1} and V_{2} are initial and final volume respectively

Here, C_{1}=0.250 M, V_{1}=2.50mL and V_{2}=100.0mL

So, C_{2}=\frac{C_{1}V_{1}}{V_{2}}

or, C_{2}=\frac{(0.250M)\times (2.50mL)}{100.0mL}

or, C_{2}=0.00625M

So, concentration of dye in diluted solution is 0.00625 M

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Which aqueous solution would have the lowest vapor pressure at 25°c 1 M NaCl?
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The question is incomplete, here is a complete question.

Which aqueous solution would have the lowest vapor pressure at 25°c.

A) 1 M NaCl

B) 1 M K_3PO_4

C) 1 M C_{12}H_{10}O_{11}

D) 1 M MgCl_2

E) 1 M C_6H_{12}O_6

Answer : The correct option is, (B) 1 M K_3PO_4

Explanation :

According to the relative lowering of vapor pressure, the vapor pressure of a component at a given temperature is equal to the mole fraction of that component of the solution multiplied by the vapor pressure of that component in the pure state.

1 M means that the 1 moles of solute present in 1 liter of solution.

Formula used :

\frac{\Delta p}{p^o}=i\times X_B

where,

p^o = vapor pressure of the pure component (water)

p_s = vapor pressure of the solution  

X_B = mole fraction of solute

i = Van't Hoff factor

As we know that the vapor pressure depends on the mole fraction of solute and the Van't Hoff factor.

So, the greater the number of particles of solute dissolved the lower the resultant vapor pressure.

(a) The dissociation of 1.0 M NaCl will be,

NaCl\rightarrow Na^++Cl^-

So, Van't Hoff factor = Number of solute particles = Na^++Cl^- = 1 + 1 = 2

(b) The dissociation of 1 M K_3PO_4 will be,

K_3PO_4\rightarrow 3K^{+}+PO_4^{3-}

So, Van't Hoff factor = Number of solute particles = 3K^{+}+PO_4^{3-} = 3 + 1 = 4

(c) The dissociation of 1 M C_{12}H_{10}O_{11} is not possible because it is a non-electrolyte solute. So, the Van't Hoff factor will be, 1.

(d) The dissociation of 1.0 M MgCl_2 will be,

MgCl_2\rightarrow Mg^{2+}+2Cl^{-}

So, Van't Hoff factor = Number of solute particles = Mg^{2+}+2Cl^{-} = 1 + 2 = 3

(e) The dissociation of 1 M C_6H_{12}O_{6} is not possible because it is a non-electrolyte solute. So, the Van't Hoff factor will be, 1.

From this we conclude that, 1 M K_3PO_4 has the highest Van't Hoff factor which means that the solution will exhibit the lowest vapor pressure.

Hence, the correct option is, (B) 1 M K_3PO_4

8 0
3 years ago
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