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erik [133]
2 years ago
11

A compound's molecular formula must always be different than the compound's empirical formula. TRUE FALSE

Chemistry
1 answer:
Juli2301 [7.4K]2 years ago
5 0

Answer: False

Explanation:

Molecular formula is the chemical formula which depicts the actual number of atoms of each element present in the compound.  

Empirical formula is the simplest chemical formula which depicts the whole number of atoms of each element present in the compound.

Example: CH_4 has similar molecular formula and empirical formula as the elements are already present in simplest of the ratios.

C_2H_2 has molecular formula of C_2H_2 but CH as the empirical formula.

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What makes the great pyramid unusual among the places on antipater’s list?
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How many atoms in 7.55 mole of Iron atom
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2 years ago
1. The heat of fusion for the ice-water phase transition is 335 kJ/kg at 0°C and 1 bar. The density of water is 1000 kg/m3 at th
vodomira [7]

Answer:

Expression for the change of melting temperature with pressure..> T₂ = T₁exp(-(P₂-P₁)/(3.61x10⁹ Pa), Freezing Point = 0°C

Explanation:

Derivation from state postulate

Using the state postulate, take the specific entropy,  , for a homogeneous substance to be a function of specific volume  and temperature  .

ds = (partial s/partial v)(t) dv + (partial s/partial T)(v) dT

During a phase change, the temperature is constant, so

ds = (partial s/partial v)(T)  dv

Using the appropriate Maxwell relation gives

ds = (partial P/partial T)(v) dv

s(β) – s(aplαha) = dP/dT (v(β) – v(α))

dP/dT = s(β) – s(α)/v(β) – v(α) = Δs/Δv

Here Δs and Δv are respectively the change in specific entropy and specific volume from the initial phase α to the final phase β.

For a closed system undergoing an internally reversible process, the first law is

du = δq – δw = Tds - Pdv

Using the definition of specific enthalpy, h and the fact that the temperature and pressure are constant, we have

du + Pdv = dh Tds,

ds = dh/T,

Δs = Δh/T = L/T

After substitution of this result into the derivative of the pressure, one finds

dp/dT = L/TΔv

<u>This last equation is the Clapeyron equation.</u>

a)

(dP/dT) = dH/TdV => dP/dlnT = dH/dV

=> dP/dlnT = dH/dV = [H(liquid) - H(solid)]/[V(liquid) - V(solid)]

= [335,000 J/kg]/[1000⁻¹ - 915⁻¹ m³/kg]

= -3.61x10⁹ J/m³ = -3.61x10⁹ Pa

=> P₂ = P₁ - 3.61x10⁹ ln(T₂/T₁) Pa

or

T₂ = T₁exp(-(P₂-P₁)/(3.61x10⁹ Pa)

b) if the pressure in Denver is 84.6 kPa:

T₂(freezing) = 273.15exp[-(84,600-100,000)/(3.61x10⁹)]

≅ 273.15 = 0°C T₁(freezing) essentially no change

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