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3 years ago

Identify the NMR term that corresponds to each description.

Chemistry

1 answer:

balandron [24]3 years ago

4 0

Answer:

A- upfield

B- down field

C- splitting

D- chemical shift

E- integration

Explanation:

NMR is a spectroscopic technique commonly used to observe the magnetic fields around the nucleus of atoms in a compound under investigation.

A chemical shift is the difference in parts per million (ppm) between the resonance frequency of the observed protons in the compound under study and that of the tetramethylsilane (TMS) (the reference compound in NMR with a chemical shift of zero ppm because all protons in the compound are equivalent).

If signals appear close to the reference signal, the signals are said to appear upfield. If the signals appear far away from the reference, they are said to appear down field.

The presence of protons cause splitting of peaks to the magnitude of n+1. n is the number of neighboring protons. Splitting refers to the appearance of multiple peaks for a single nucleus due to neighboring nuclei.

The area of a signal that corresponds to the number of nuclei at that frequency is called the integration.

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Answer:

The molarity is 0.56 $\frac{moles}{L}$

Explanation:

In a mixture, the chemical present in the greatest amount is called a solvent, while the other components are called solutes. Then, the molarity or molar concentration is the number of moles of solute per liter of solution.

In other words, molarity is the number of moles of solute that are dissolved in a given volume.

The Molarity of a solution is determined by:

$Molarity (M)=\frac{number of moles of solute}{Volume}$

Molarity is expressed in units ( $\frac{moles}{liter}$ ).

Then you must know the number of moles of Cu(NO₂)₂. For that it is necessary to know the molar mass. Being:

Cu: 63.54 g/mol
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the molar mass of Cu(NO₂)₂ is:

Cu(NO₂)₂= 63.54 g/mol + 2*(14 g/mol + 2* 16 g/mol)= 155.54 g/mol

Now the following rule of three applies: if 155.54 g are in 1 mole of the compound, 225 g in how many moles are they?

$moles=\frac{225 g*1 mole}{155.54 g}$

moles= 1.45

So you know:

number of moles of solute= 1.45 moles
volume=2.59 L

Replacing in the definition of molarity:

$Molarity=\frac{1.45 moles}{2.59 L}$

Molarity= 0.56 $\frac{moles}{L}$

The molarity is 0.56 $\frac{moles}{L}$

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Answer:

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