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ankoles [38]
3 years ago
9

5. Given that a 40.14 g sample of hydrated NiSO4•XH2O is reduced in mass to 2.14 g upon heating.

Chemistry
1 answer:
Ahat [919]3 years ago
4 0
<h3>Answer:</h3>

Value of X is 7

<h3>Explanation:</h3>

We are given;

  • Mass of the Hydrated sample as 40.14 g
  • Mass of the anhydrous salt as 22.14 g (Missing in the question)

We are required to determine the value of X in the hydrated sample, NiSO4•XH2O .

  • First, we determine the mass of the anhydrous salt
  • Mass of water of crystallization = Mass hydrate sample - Mass of  anhydrous sample

                                      = 40.14 g - 22.14 g

                                      = 18.0 g

We can determine the value of X by determine simple number ratio of anhydrous compound and water molecules.

  • Determine the number of moles
  • Molar mass of NiSO₄ = 154.75 g/mol
  • Moles of NiSO₄ = 22.14 g ÷ 154.75 g/mol

                                  = 0.1431 mole

Molar mass of water = 18.02 g/mol

Moles of water = 18.0 g  ÷ 18.02 g/mol

                          = 1.00 mole

We can then determine the mole ratio.

Mole ratio = 0.1431 mole : 1.00 mole

                 = 0.1431 mole/0.1431 mole : 1.00 mole/0.1421 mole

                 = 1 : 7.03

                = 1 : 7

Therefore, the formula of the hydrated salt is NiSO₄•7H₂O

Thus, the value of X is 7

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What pH is needed to produce this value of Q if the concentration and pressure values are [Br2]=2.50×10?4M, [Br?]=11.85M, [SO42?
Bingel [31]

Explanation:

The given reaction will be as follows.

       2H_{2}O + Br_{2} + SO_{2} \rightarrow 2Br^{-} + SO^{2-}_{4} + 4H^{+}

Hence, expression that represents relation between given reaction and Q will be as follows.

              Q = \frac{[Br^{-}]^{2}[SO^{2-}_{4}][H^{+}]^{4}}{[Br_{2}]P_{SO_{4}}}

          1.4 \times 10^{-26} = \frac{(11.85)^{2} \times (8.35) \times [H^{+}]^{4}}{(2.5 \times 10^{4}) \times 2.50 \times 10^{5}}

                [H^{+}]^{4} = 7.46 \times 10^{-34}

                 [H^{+}]= 5.22 \times 10^{-10}

As relation between pH and [H^{+}] is as follows.

                     pH = -log [H^{+}]

                           = -log 5.22 \times 10^{-10}

                           = -(0.717 - 10)

                           = 9.28

Thus, we can conclude that the pH needed to produce the given value of Q is 9.28.

4 0
3 years ago
How many grams of lead(II) nitrate must be dissolved in 1.00 L of water to produce a solution that is 0.300 M in total dissolved
MrRa [10]

Answer:

A solution that is 0.100 M (i.e. 33,12 g of lead (II) nitrate in 1.00 L of water) yields the desired total dissolved ions concentration.

Explanation:

The molecular formula of lead (II) nitrate is Pb(NOPb(NO_{3} )_{2} and its molecular mass is 331,2 g/mol.

In disolution, the equilibrium will look like this:

Pb(NOPb(NO_{3} )_{2} -> Pb^{2+}  + 2(NO)_{3} ^{-1}

The equation above means that, one mol of lead (II) nitrate dissolved in 1L will yield one mol of Pb ions and 2 moles of NO3 ions, i.e. 3 moles total.

If we dissolve 0.100 moles of lead (II) nitrate in 1.00 L of water, the stoichiometry of the disolution states that in turn, it will yield 0.100 of Pb ions and 0.200 moles of NO3 ions, i.e. 0.300 M in total dissolved ions.

331,2 g/mol * 0.100 mol/L * 1 L = 33,12 grams of the compound are required.

6 0
4 years ago
The compound cisplatin, pt(nh3)2cl2 , has been studied extensively as an antitumor agent.
Nataliya [291]

a. Elemental percent composition is the mass percent of each element in the compound.

The formula for mass elemental percent composition = \frac{mass of element}{mass of compound}   (1)

The molecular formula of cisplatin is Pt(NH_3)_2Cl_2.

The atomic weight of the elements in cisplatin is:

Platinum, Pt = 195.084 u

Nitrogen, N = 14.0067 u

Hydrogen, H = 1 u

Chlorine, Cl = 35.453 u

The molar mass of Pt(NH_3)_2Cl_2 = 195.084+ (2\times 14.0067)+(6\times 1)+(2\times 35.453) = 300.00 g/mol

The mass of each element calculated using formula (1):

- Platinum, Pt %

\frac{195.084}{300.00} \times 100 = 65.23%.

- Nitrogen, N%

\frac{2\times 14.0067}{300.00} \times 100 = 9.34%

- Hydrogen, H%

\frac{6\times 1}{300.00} \times 100 = 2.0%

- Chlorine, Cl%

\frac{2\times 35.453}{300.00} \times 100 = 23.63%

b. The given reaction of cisplatin is:

K_2PtCl_4(aq)+2NH_3(aq)\rightarrow Pt(NH_3)_2Cl_2(s)+2KCl(aq)

According to the balanced reaction, 1 mole of K_2PtCl_4 gives 1 mole of Pt(NH_3)_2Cl_2.

Now, calculating the number of moles of K_2PtCl_4 in 100.0 g.

Number of moles = \frac{given mass}{Molar mass}

Molar mass of K_2PtCl_4 = 2\times 39.0983+195.084+4\times 35.453 = 415.093 g/mol

Number of moles of K_2PtCl_4 = \frac{100 g}{415.093 g/mol} = 0.241 mole.

Since, 1 mole of K_2PtCl_4 gives 1 mole of Pt(NH_3)_2Cl_2. Therefore, mass of cisplatin is:

0.241 mole\times 300 g/mol = 72.3 g

For mass of KCl:

Molar mass of KCl = 39.0983 + 35.453 = 74.55 g/mol

Since, 1 mole of K_2PtCl_4 gives 2 mole of KCl. Therefore, mass of KCl is:

0.241 mole\times 74.55 g/mol\times 2 = 35.93 g


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Calculate the mass (in g) of a single starch molecule (c6h10o5).
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That looks complicated
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