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Nookie1986 [14]
3 years ago
6

SO

Chemistry
1 answer:
Burka [1]3 years ago
7 0

Answer:

\large \boxed{\text{E) 721 K; B) 86.7 g}}

Explanation:

Question 7.

We can use the Combined Gas Laws to solve this question.

a) Data

p₁ = 1.88 atm; p₂ = 2.50 atm

V₁ = 285 mL;  V₂ = 435 mL

T₁ = 355 K;     T₂ = ?

b) Calculation

\begin{array}{rcl}\dfrac{p_{1}V_{1}}{T_{1}}& =&\dfrac{p_{2}V_{2}}{T_{2}}\\\\\dfrac{1.88\times285}{355} &= &\dfrac{2.50\times 435}{T_{2}}\\\\1.509& = &\dfrac{1088}{T_{2}}\\\\1.509T_{2} & = & 1088\\T_{2} & = & \dfrac{1088}{1.509}\\\\ & = & \textbf{721K}\\\end{array}\\\text{The gas must be heated to $\large \boxed{\textbf{721 K}}$}

Question 8. I

We can use the Ideal Gas Law to solve this question.

pV = nRT

n = m/M

pV = (m/M)RT = mRT/M

a) Data:

p = 4.58 atm

V = 13.0 L

R = 0.082 06 L·atm·K⁻¹mol⁻¹

T = 385 K

M = 46.01 g/mol

(b) Calculation

\begin{array}{rcl}pV & = & \dfrac{mRT}{M}\\\\4.58 \times 13.0 & = & \dfrac{m\times 0.08206\times 385}{46.01}\\\\59.54 & = & 0.6867m\\m & = & \dfrac{59.54}{0.6867 }\\\\ & = & \textbf{86.7 g}\\\end{array}\\\text{The mass of NO$_{2}$ is $\large \boxed{\textbf{86.7 g}}$}

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Therefore, molar conductivity (\Lambda_{m}) of monobasic acid is calculated as follows.

                 \Lambda_{m} = \frac{conductivity}{concentration}

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                                 = \frac{5.07 \times 10^{-2} S m^{-1}}{0.01 mol \times 10^{3}}

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                             = \frac{5.07 \times 10^{-2} S m^{-1}}{4.043 \times 10^{-2} S m^{2} mol^{-1}}

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                     K = \frac{c \times \alpha^{2}}{1 - \alpha}

Putting the values into the above formula we get the following.

                     K = \frac{c \times \alpha^{2}}{1 - \alpha}

                        = \frac{0.01 \times (0.1254)^{2}}{1 - 0.1254}

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Also, relation between pK_{a} and K_{a} is as follows.

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                              = -log (1.7973 \times 10^{-4})

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