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2 years ago

Consider the equation below.

Chemistry

1 answer:

Ksenya-84 [330]2 years ago

8 0

Answer:

1 : 1

Explanation:

We know that the equation is balanced because the number of zinc, hydrogen, sulfur and oxygen atoms are the same in both sides of the equation.

Zn + H2SO4 → ZnSO4 + H2

We can see that there is one molecule for Zn and also one molecule for ZnSO4 (we know this because there are no numbers before the formulas, so the 1 is implied)

That is why the mole ratio of zinc to zinc sulfate is 1 : 1

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Sulfonation of benzene has the following mechanism: (1) 2 H2SO4 ⇌ H3O+ + HSO4− + SO3 [fast] (2) SO3 + C6H6 → H(C6H5+)SO3− [slow]

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Question is incomplete, complete question is as follows :

Complete Question : .Sulfonation of benzene has the following mechanism:

(1) 2 H2SO4 ⇌ H3O+ + HSO4− + SO3

[fast]

(2) SO3 + C6H6 → H(C6H5+)SO3−

[slow]

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[fast]

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Rate=k(________/_________)

Answer:

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Explanation :

Frist of all, all the common terms are cancelled out and written the overall reaction.

As we know that the rate depednant step is the slowest step of the reaction, rate law is :

rate = $k_{2} [SO_{3}][C_{6}H_{6}]$

But the problem is that SO3 cannot be written in the overall rate law because it is an intermediate.

Rate law for synthesis of S03 is as follows :

rate = $k_{1}[H_{2}SO_{4}]^{2}$

Hence when we substitute equation 2 in equation one,

Rate comes out to be = $k_{overall} [H_{2}SO_{4}]^{2} [C_{6}H_{6}]$

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2 years ago