An ambient pressure of 1 atm
Answer:
A) Sample B has more calcium carbonate molecules
Explanation:
M = Molar mass of calcium carbonate = 100.0869 g/mol
= Avogadro's number = 
For the 4.12 g sample
Moles of a substance is given by

Number of molecules is given by

For the 19.37 g sample

Number of molecules is given by


So, sample B has more calcium carbonate molecules.
The ratio of the elements of carbon, oxygen, calcium atoms, ions, has to be same in both the samples otherwise the samples cannot be considered as calcium carbonate. Same is applicable for impurities. If there are impurites then the sample cannot be considered as calcium carbonate.
The amount of kinetic energu has depens upon an object's speed and its mass.
So its I and IV.
The correct answer is B.
Hope it helps!
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