Answer: The change in entropy change when 207 g of toluene boils at
is 223
.
Explanation:
It is given that mass of toulene is 207 g and its molar mass is 92.14 g/mol. So, its moles will be calculated as follows.
No. of moles = 
= 
= 2.25 moles
As we are given that heat of vaporization for 1 mol is 38.1 kJ/mol. So, heat of vaporization for 2.25 moles will be calculated as follows.

= 85.725 KJ
Now, we know that the relation between enthalpy change and entropy change is as follows.

= 
= 0.223 
or, = 223
(as 1 kJ = 1000 J)
Thus, we can conclude that the change in entropy change when 207 g of toluene boils at
is 223
.
Answer:
2.50 atm
Explanation:
We have 10.4 g of DDT (solute), whose molar mass is 354.50 g/mol. The corresponding moles are:
10.4 g × (1 mol/354.50 g) = 0.0293 mol
The molarity of the solution is:
M = moles of solute / liters of solution
M = 0.0293 mol / 0.286 L
M = 0.102 M
We can find the osmotic pressure (π) using the following pressure.
π = M × R × T
where,
R: ideal gas constant
T: absolute temperature
π = M × R × T
π = 0.102 M × 0.0821 atm.L/mol.K × 298 K
π = 2.50 atm
The answer is the trachea
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