101.325 kPa = 760 mmHg. So, 25.0 kPa is

An equilibrium mixture of PCl5(g), PCl3(g), and Cl2(g) has partial pressures of 217.0 Torr, 13.2 Torr, and 13.2 Torr, respective

djverab [1.8K]

Answer:

The new partial pressures after equilibrium is reestablished for $PCl_3$ :

$P_1'=6.798 Torr$

The new partial pressures after equilibrium is reestablished $Cl_2$ :

$P_2'=26.398 Torr$

The new partial pressures after equilibrium is reestablished for $PCl_5$ :

$P_3'=223.402 Torr$

Explanation:

$PCl_3(g) + Cl_2(g)\rightleftharpoons PCl_5(g)$

At equilibrium before adding chlorine gas:

Partial pressure of the $PCl_3=P_1=13.2 Torr$

Partial pressure of the $Cl_2=P_2=13.2 Torr$

Partial pressure of the $PCl_5=P_3=217.0 Torr$

The expression of an equilibrium constant is given by :

$K_p=\frac{P_1}{P_1\times P_2}$

$=\frac{217.0 Torr}{13.2 Torr\times 13.2 Torr}=1.245$

At equilibrium after adding chlorine gas:

Partial pressure of the $PCl_3=P_1'=13.2 Torr$

Partial pressure of the $Cl_2=P_2'=?$

Partial pressure of the $PCl_5=P_3'=217.0 Torr$

Total pressure of the system = P = 263.0 Torr

$P=P_1'+P_2'+P_3'$

$263.0Torr=13.2 Torr+P_2'+217.0 Torr$

$P_2'=32.8 Torr$

$PCl_3(g) + Cl_2(g)\rightleftharpoons PCl_5(g)$

At initail

(13.2) Torr (32.8) Torr (13.2) Torr

At equilbriumm

(13.2-x) Torr (32.8-x) Torr (217.0+x) Torr

$K_p=\frac{P_3'}{P_1'\times P_2'}$

$1.245=\frac{(217.0+x)}{(13.2-x)(32.8-x)}$

Solving for x;

x = 6.402 Torr

The new partial pressures after equilibrium is reestablished for $PCl_3$ :

$P_1'=(13.2-x) Torr=(13.2-6.402) Torr=6.798 Torr$

The new partial pressures after equilibrium is reestablished $Cl_2$ :

$P_2'=(32.8-x) Torr=(32.8-6.402) Torr=26.398 Torr$

The new partial pressures after equilibrium is reestablished for $PCl_5$ :

$P_3'=(217.0+x) Torr=(217+6.402) Torr=223.402 Torr$

5 0

2 years ago

How many milliliters of an aqueous solution of 0.193 M potassium carbonate is needed to

VikaD [51]

Answer:

295 mL

Explanation:

Given data:

Volume needed = ?

Molarity of solution = 0.193 M

Mass of salt = 7.90 g

Solution:

Molarity = number of moles of solute / volume in L

Number of moles of salt = mass/molar mass

Number of moles of salt = 7.90 g/ 138.205 g/mol

Number of moles = 0.057 mol

Volume needed:

Molarity = number of moles / volume in L

0.193 M = 0.057 mol / volume in L

Volume in L = 0.057 mol / 0.193 M

Volume in L = 0.295 L

L into mL

0.295 L × 1000 mL/1L

295 mL

6 0

2 years ago

A nonvolatile solute is dissolved in benzene so that it has a mole fraction of 0.139. What is the vapor pressure of the solution

lapo4ka [179]

Answer:

The vapor pressure of the solution is 3.69 torr

Explanation:

Step 1: Data given

Mole fraction of benzene in the solution = 0.139

P° of benzene is 26.5 torr

Step 2: Calculate the vapor pressure of the solution

Psolution = Xbenzene * P°benzene

⇒with Psolution = the vapor pressure of the solution

⇒with Xbenzene = the mole fraction of benzene = 0.139

⇒with P°benzene = the vapor pressure of pure benzene = 26.5 torr

Psolution = 0.139 * 26.5 torr

Psolution = 3.69 torr

The vapor pressure of the solution is 3.69 torr

7 0

2 years ago

How can we make use of acids or bases to Prevent the growth of microorganisms in swimming pools?

pentagon [3]

By putting smarticle particles

8 0

3 years ago

Write this in a word and skeleton equation:

DiKsa [7]

Answer:

Write this in a word and skeleton equation:

Solid silver chloride and an aqueous solution of nitric acid are produced when a solution of silver nitrate is reacted with a solution of hydrochloric acid.

Explanation:

6 0

2 years ago