Deduce the structure of an unknown compound using the data below: Molecular Formula: C6H12O IR: 1705 cm-1 1H NMR: no absorptions
greater than δ 3 ppm 13C NMR: δ 24.4, δ 26.4, δ 44.2, and δ 212.6 ppm. Resonances at δ 44.2 and 212.6 have very low intensity.
1 answer:
Answer:
The compound elucidated from the spectral data is <u>4-methyl penta-2-none</u>
Explanation:
- <u>1700 cm-1 from IR data</u> suspects aldehyde/ketone or carboxylic acid. However,since the peak is not a stretched vibration, it implies an aldehyde or ketone present.
- <u>3 ppm H NMR</u> confirms O-CH3 bond
- <u>24.4 13C NMR</u> confirms CH3-R bond
- 26.4 13C NMR confirms H3C-(R)C(H)-R
- 44.2 13C NMR Confirms C=
- 2126 13C NMR confirms aldehyde C=O bond
<u>The deduced structure is 4-methyl penta-2-one (see attached) </u>given multiple CH3 atoms.
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Answer:
Explanation: <u>Heats</u> <u>of</u> <u>formation</u> is the amount of heat necessary to create 1 mol of a compound from its molecular constituents. The basic conditions the substance is formed is at standard conditions: 1 atm and 25°C. Each compound has its own heat of formation per mol of compound (kJ/mol), but to an element is assigned a value of zero.
<u>Standard</u> <u>Enthalpy</u> <u>Change</u> is defined as the heat absorbed or released when a reaction takes place. It can be positive or negative, which means reaction is endothermic or exothermic, respectively.
Enthalpy change is calculated as the difference between the sum of heat formation of products and the sum of heat formation of the reactants:
For the reaction
2NH₃ + 3N₂O → 4N₂ + 3H₂O
2(-46.2) + 3(82.05) 4(0) + 3(-241.8)
<u>The standard enthalpy change for the reaction is </u><u> kJ</u>