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zmey [24]
4 years ago
8

Deduce the structure of an unknown compound using the data below: Molecular Formula: C6H12O IR: 1705 cm-1 1H NMR: no absorptions

greater than δ 3 ppm 13C NMR: δ 24.4, δ 26.4, δ 44.2, and δ 212.6 ppm. Resonances at δ 44.2 and 212.6 have very low intensity.

Chemistry
1 answer:
Novosadov [1.4K]4 years ago
7 0

Answer:

The compound elucidated from the spectral data is <u>4-methyl penta-2-none</u>

Explanation:

  • <u>1700 cm-1 from IR data</u> suspects aldehyde/ketone or carboxylic acid. However,since the peak is not a stretched vibration, it implies an aldehyde or ketone present.
  • <u>3 ppm H NMR</u> confirms O-CH3 bond
  • <u>24.4 13C NMR</u> confirms CH3-R bond
  • 26.4 13C NMR  confirms H3C-(R)C(H)-R
  • 44.2 13C NMR Confirms C=
  • 2126 13C NMR confirms aldehyde C=O bond

<u>The deduced structure is 4-methyl penta-2-one (see attached) </u>given multiple CH3 atoms.

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You find a little bit (0.150g) of a chemical marked Tri-Nitro-Toluene. Upon complete combustion in oxygen, you collect 0.204 g o
Elan Coil [88]

Answer:

The empirical formula is C7H5N3O6  

Explanation:

Step 1: Data given

Mass of sample = 0.150 grams

Mass of CO2 = 0.204 grams

Molar mass CO2 = 44.01 g/mol

Mass of H2O = 0.030 grams

Molar mass H2O = 18.02 g/mol

Molar mass C = 12.01 g/mol

Molar mass H = 1.01 g/mol

Molar mass O = 16.0 g/mol

Step 2: Calculate moles CO2

Moles CO2 = mass CO2 / molar mass CO2

Moles CO2 = 0.204 grams / 44.01 g/mol

Moles CO2 = 0.00464 moles

Step 3: Calculate moles C

For 1 mol CO2 we have 1 mol C

For 0.00464 moles we have 0.00464 moles C

Step 4: Calculate mass C

Mass C = 0.00464 moles * 12.01 g/mol

Mass C = 0.0557 grams

Step 5: Calculate moles H2O

Moles H2O = 0.030 grams / 18.02 g/mol

Moles H2O = 0.00166 moles

Step 6: Calculate moles H

For 1 mol H2O we have 2 moles H

For 0.00166 moles H2O we have 2* 0.00166 = 0.00332 moles H

Step 7: Calculate mass H

Mass H = 0.00332 moles * 1.01 g/mol

Mass H = 0.00335 grams

Step 8: Calculate mass N

Mass N = 0.185 * 0.150 grams

Mass N = 0.02775 grams

Step 9: Calculate moles N

Moles N = 0.02775 grams / 14.0 g/mol

Moles N = 0.00198 moles

Step 10: Calculate mass O

Mass O = 0.150 grams - 0.02775 - 0.00335 - 0.0557

Mass O = 0.0632 grams

Step 11: Calculate moles O

Moles O = 0.0632 grams / 16.0 g/mol

Moles O = 0.00395 moles

Step 11: Calculate mol ratio

We divide by the smallest amount of moles

C: 0.00464 moles / 0.00198 moles =2.33

H: 0.00332 moles / 0.00198 moles = 1.66

N: 0.00198 moles / 0.00198 moles = 1

O: 0.00395 moles / 0.00198 moles = 2

For 1 mol N we have 2.33 moles C, 1.66 moles H and 2 moles O

OR

For 3 moles N we have 7 moles C, 5 moles H and 6 moles O

The empirical formula is C7H5N3O6  

5 0
3 years ago
How does adding a non-volatile solute to a pure solvent affect the boiling point of the pure solvent?
belka [17]
The correct answer is the second statement. The solvent will have a higher boiling point. Adding a non-volatile solute to a pure solvent will increase the boiling point of the solvent. This solution exhibit colligative properties. Colligative properties depend on the amount of solute dissolved in a solvent. These set of properties do not depend on the type of species present. 
7 0
4 years ago
Determine the mass of CaCO3 required to produce 40.0 mL CO2 at STP. Hint use molar volume of an ideal gas (22.4 L)
cupoosta [38]

Answer:

m_{CaCO_3}=0.179gCaCO_3

Explanation:

Hello,

In this case, since the undergoing chemical reaction is:

CaCO_3(s)\rightarrow CaO(s)+CO_2(g)

The corresponding moles of carbon dioxide occupying 40.0 mL (0.0400 L) are computed by using the ideal gas equation at 273.15 K and 1.00 atm (STP) as follows:

PV=nRT\\\\n=\frac{PV}{RT}=\frac{1.00 atm*0.0400L}{0.082\frac{atm*L}{mol*K}*273.15 K})=1.79x10^{-3} mol CO_2

Then, since the mole ratio between carbon dioxide and calcium carbonate is 1:1 and the molar mass of the reactant is 100 g/mol, the mass that yields such volume turns out:

m_{CaCO_3}=1.79x10^{-3}molCO_2*\frac{1molCaCO_3}{1molCO_2} *\frac{100g CaCO_3}{1molCaCO_3}\\ \\m_{CaCO_3}=0.179gCaCO_3

Regards.

3 0
4 years ago
The pile-up of sand and silt at the site where a river flows into the ocean forms a
Ivanshal [37]

Answer:

As a river flows, it picks up sediment from the river bed, eroding banks, and debris on the water. The river mouth is where much of this gravel, sand, silt, and clay—called alluvium—is deposited. When large amounts of alluvium are deposited at the mouth of a river, a delta is formed.

Explanation:

7 0
3 years ago
Read 2 more answers
Calculate the standard molar enthalpy of formation for Na2O(s), given that the standard enthalpy of formation for Na2O2(s) is -5
Anarel [89]

Answer:

- 416 kJ/mol

Explanation:

The standard enthalpy of the reaction (Δ H ∘ rxn) is independent of the pathway, so it can be calculated by the enthalpy of formation of the reactants and the products:

Δ H ∘ rxn = ∑n*Δ H ∘f products - ∑n*Δ H ∘f reactants

Where n is the number of moles in the balanced reaction. So, for the reaction given:

Na₂O(s) + 1/2O₂(g) → Na₂O₂(s)

Because O₂ is formed by only one elements, its Δ H ∘f is 0 kJ/mol:

-89.0 = (1*(-505) - (1*Δ H ∘fNa₂O)

Δ H ∘fNa₂O = -505 + 89

Δ H ∘fNa₂O = - 416 kJ/mol

3 0
4 years ago
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