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marin [14]
3 years ago
12

Which of the following is the correct ( unbalanced) equation for the reaction that takes place when solid phosphorus combines wi

th oxygen gas to form diphosphorus pentoxide?
A. P(s) + O2(g) --> P2O5(s)

B. P2O5(s) --> P2(s) + O2(g)

C. P(s) + O(g) --> P5O2(g)

D. P(s) + O2(g) --> PO2(g)
Chemistry
1 answer:
MA_775_DIABLO [31]3 years ago
8 0

Answer: option A

P(s) + O2(g) --> P2O5(s)

Explanation:

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Calculate the pH for each of the following cases in the titration of 25.0 mL of 0.150 M acetic acid (Ka = 1.75x10-5) with 0.150
mylen [45]

Answer:

a) pH = 2.793

b) pH = 4.280

c) pH = 4.933

d) pH = 8.816

e) pH = 8.861

f) pH = 8.891

Explanation:

a) VNaOH = 0 mL

∴ CH3COOH ↔ CHECOO- + H3O+

⇒ Ka = 1.75 E-5 = [ H3O+ ] * [ CH3COO-] / [ CH3COOH ]

mass balance:

⇒ <em>C</em> CH3COOH = [ CH3COO- ] + [ CH3COOH ] = 0.150 M

charge balance:

⇒ [ H3O+ ] = [ CH3COO- ]

⇒ Ka = 1.75 E-5 = [ H3O+ ]² / ( 0.150 M - [ H3O+ ] )

⇒ [ H3O+ ]² + 1.75 E-5 [ H3O+ ] - 2.625 E-6 = 0

⇒ [ H3O+ ] = 1.61146 E-3 M

⇒ pH = - Log [ H3O+ ] = 2.793

b) after  5.0 mL NaOH:

∴ CH3COOH + NaOH ↔ CH3COONa + H2O

⇒ <em>C</em> NaOH = (5 E-3 L * 0.150 mol/L) / (0.025+0.01 ) = 0.02143 M

⇒ <em>C</em> CH3COOH = ((0.025*0.150) - (0.01*0.150)) / (0.025 + 0.01) = 0.0643 M

mass balance:

⇒ 0.02143 + 0.0643 = [ CH3COOH ] + [ CH3COO- ] = 0.086 M

charge balance:

⇒ [ H3O+ ] + [Na ] = [ CH3COO- ]

⇒ [ H3O+ ] + 0.02143 = [ CH3COO- ]

⇒ Ka = [ H3O+ ] * ( [ H3O+ ] + 0.150 ) / (0.086 - 0.02143 - [ H3O+ ]) = 1.75 E-5

⇒ [ H3O+ ]² + 0.02143 [ H3O+ ] = 1.13 E-6 - 1.75 E-5 [ H3O+ ]

⇒ [ H3O+ ]² + 0.02144 [ H3O+ ] - 1.13 E-6 = 0

⇒ [ H3O+ ] = 5.26 E-5 M

⇒ pH = 4.28

c) after 15 mL NaOH:

⇒ <em>C</em> CH3COOH = 0.0375 M

⇒ <em>C</em> NaOH = 0.05625 M

mass balance:

⇒ 0.09375 M = [ CH3COO- ] +[ CH3COOH ]

charge balance:

⇒ [ H3O+ ] + 0.05625 = [ CH3COO- ]

⇒ Ka = 1.75 E-5 = [ H3O+ ] * ([ H3O+ ] + 0.05625) / (0.09375 - 0.05625 - [H3O+])

⇒ [H3O+]² + 0.05625[H3O+] = 6.5625 E-7 - 1.75 E-5 [H3O+]

⇒ [ H3O+]² + 0.05626[H3O+] - 6.5625 E-7 = 0

⇒ [ H3O+ ] = 1.1662 E-5 M

⇒ pH = 4.933

d) after 25 mL NaOH:

⇒ <em>C </em>NaOH = 0.075 M

⇒ <em>C</em> CH3COOH = 0 M....equiv. point

⇒Kh = Kw/Ka = 1 E-14 / 1.75 E-8 = 5.7143 E-10 = [ OH-]² / ( 0.075 - [OH-])

⇒ [OH-]² + 5.7143 E-10[OH-] - 4.286 E-11 = 0

⇒ [ OH- ] = 6.5463 E-6 M

⇒ pOH = 5.184

⇒ pH = 8.816

e) after 40 mL NaOH:

⇒ <em>C </em>NaOH = 0.0923 M

⇒ [OH-]² + 5.7143 E-10 [OH-] - 5.275 E-11 = 0

⇒ [OH-] = 7.2624 E-6 M

⇒ pOH = 5.139

⇒ pH = 8.861

f) after 60 mL NaOH:

⇒ <em>C </em>NaOH = 0.106 M

⇒ [OH-]² + 5.7143 E-10 [OH-] - 6.05 E-11 = 0

⇒ [OH-] = 7.7782 E-6 M

⇒ pOH = 5.11

⇒ pH = 8.891

5 0
3 years ago
Select the single best answer. Explain the observed trend in the melting points for four isomers of molecular formula C7H16. mp
damaskus [11]

Answer:

The ability of the molecule to pack more tightly increases the melting point.

Explanation:

In hydrocarbons of same molecular formula, melting point is determined by:

  • weak intermolecular forces
  • Molecular symmetry

Higher the intermolecular forces and molecular symmetry, higher will be the melting point.

Intermolecular forces in hydrocarbons decreases with branching. Moreover, branching interfere the tight packing of the molecule in the crystal. Therefore, branched hydrocarbons tend to have lower melting point.

However, in highly branched hydrocarbons molecular symmetry increases which results in tight packing of the molecule in the crystal.

So, highly tight packed molecules tend to have high melting point.

As (CH3)2CHC(CH3)3 is highly branched and has high molecular symmetry, therefore, its melting point is highest among given.

So, among the given, option c is correct.

5 0
2 years ago
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