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Nataliya [291]
3 years ago
11

An X-ray beam with λ = 157 pm incident on the surface of a crystal produced a maximum reflection at an angle of θ = 28.5 ∘. Assu

ming n=1, calculate the separation between layers of atoms in the crystal.
Chemistry
1 answer:
WARRIOR [948]3 years ago
8 0

Answer:

The separation between layers of atoms in the crystal is 164.52 pm.

Explanation:

Formula used

n \lambda = 2d\sin \theta (Bragg's law)

Where :

n = an order of reflection (integer)

\lambda = wavelength of the beam incident X-ray

d = spacing between the layer

θ = incident angle ( angle between ray and scatter plane)

We have :

λ = 157 pm

θ = 28.5°

n = 1

d = ?

1\times 157 pm= 2d\sin (28.5^o) (Bragg's law)

d=\frac{1\times 157 pm}{2\times \sin (28.5^o)}=164.52 pm

The separation between layers of atoms in the crystal is 164.52 pm.

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Refraction occurs when light crosses the interface between two mediums with different optical density; when this happens, the light bends and also changes speed.

The angle at which the ray of light is refracted into the second medium depends on the optical density of the two mediums, but also on the wavelength of the light.

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How do you calculate the number of moles in CO2
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Answer:

The number of molecules in a mole (known as Avogadro's constant) is defined such that the mass of one mole of a substance, expressed in grams, is equal to the mean molecular mass of the substance. The molecular mass of CO2 = 12+2x16 = 44, so the mass of a mole of CO2 is approximalty 44 grams

Explanation:

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2 years ago
The following questions pertain to a system contains 122 g CO(g) in a 0.400 L container at -71.2 degrees C.
7nadin3 [17]

Answer:

a. P = 182 atm

Explanation:

Data Given:

amount of CO = 122g

Volume of CO = .400 L

Temperature of CO =  -71.2°C

Convert the temperature to Kelvin

T = °C + 273

T =  -71.2 + 273

T =  201.8 K

a. Calculate the pressure exerted by the CO(g) in this system using the ideal gas equation (P) = ?

Solution:

To calculate Pressure by using ideal gas formula

                  PV = nRT

Rearrange the equation for Pressure

                   P = nRT / V . . . . . . . . . (1)

where

P = pressure

V = Volume

T= Temperature

n = Number of moles

R = ideal gas constant = 0.08206 L.atm / mol. K

For this we have to know the mole of the gas and the following formula will be used

                 no. of moles = mass in grams / molar mass . . . . . . (2)

Molar mass of CO = 12 + 16 = 28 g/mol

Put values in equation 2

                no. of moles = 122 g / 28 g/mol

                no. of moles = 4.4 mol

Now put the value in formula (1) to calculate Pressure for CO

P = 4.4 x 201.8 K x 0.08206 (L.atm/mol. K) / 0.400 L

P = 182 atm

So the pressure will be 182 atm

__________

b. Data Given:

Actual pressure exerted by CO = 145 atm

expected pressure exerted by CO = 182 atm

why the actual pressure is less than what would be expected = ?

Explanation:

This is because of the deviation from ideal behavior of real gases.

The real gases approach to ideal behavior under very high temperature and very low pressure.

But CO deviate from ideal behavior to give expected value for pressure, because it behave at high pressure and low temperature.

This non-ideal behavior is due to two postulate of ideal behavior

  • gas molecules have negligible volume
  • Gas molecules have negligible inter-molecular interaction

but these postulates not obeyed under real condition. so we calculated the pressure using ideal condition values for gas and obtained the expected value for pressure but the actual pressure value was detected under normal condition.

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