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erik [133]
3 years ago
6

Rank the following groups in terms of their priority according to the Cahn-Ingold-Prelog system of priorities. Give the highest

ranking group a priority of 1 and the lowest ranking group a priority of 4.
a. D
b. H
c. NH2
d. CH2OH
Chemistry
1 answer:
goblinko [34]3 years ago
4 0

Answer:

<h2>(1). NH_{2} </h2><h2>(2). CH_{2}OH</h2><h2>(3). D</h2><h2>(4). H</h2>

Explanation:

Cahn, Ingold, and Prelog formulated a rule to specify the arrangement of the atoms or groups that are present in an asymmetric molecule. This rule is called a Cahn-Ingold-Prelog system. This system is generally used in the R, S system of nomenclature.

          According to this rule, such an atom that is directly linked to the asymmetric carbon atom is given the highest priority that has the highest atomic number. So here  Nitrogen atom of NH_{2} molecule is given the highest priority because Nitrogen has 7 atomic numbers. Carbon atom of CH_{2}OH molecule  has 6 atomic number. So it is given 2nd position. Deuterium and Hydrogen have 2 and 1 atomic numbers respectively so the are given 3rd and 4th order respectively.                                                                                                                  

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This an incomplete question, here is a complete question.

Calculate the empirical formula for each stimulant based on its elemental mass percent composition.

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(b) The empirical formula for the given compound is C_4H_5N_2O

Explanation:

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Let the mass of compound be 100 g. So, percentages given are taken as mass.

Mass of C = 74.03 g

Mass of H = 8.70 g

Mass of N = 17.27 g

To formulate the empirical formula, we need to follow some steps:

Step 1: Converting the given masses into moles.

Moles of Carbon =\frac{\text{Given mass of Carbon}}{\text{Molar mass of Carbon}}=\frac{74.03g}{12g/mole}=6.17moles

Moles of Hydrogen = \frac{\text{Given mass of Hydrogen}}{\text{Molar mass of Hydrogen}}=\frac{8.70g}{1g/mole}=8.70moles

Moles of Nitrogen = \frac{\text{Given mass of nitrogen}}{\text{Molar mass of nitrogen}}=\frac{17.27g}{14g/mole}=1.23moles

Step 2: Calculating the mole ratio of the given elements.

For the mole ratio, we divide each value of the moles by the smallest number of moles calculated which is 1.23 moles.

For Carbon = \frac{6.17}{1.23}=5.01\approx 5

For Hydrogen  = \frac{8.70}{1.23}=7.07\approx 7

For Nitrogen = \frac{1.23}{1.23}=1

Step 3: Taking the mole ratio as their subscripts.

The ratio of C : H : N = 5 : 7 : 1

The empirical formula for the given compound is C_5H_7N_1=C_5H_7N

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We are given:

Percentage of C = 49.48 %

Percentage of H = 5.19 %

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Percentage of O = 16.48 %

Let the mass of compound be 100 g. So, percentages given are taken as mass.

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To formulate the empirical formula, we need to follow some steps:

Step 1: Converting the given masses into moles.

Moles of Carbon = \frac{\text{Given mass of Carbon}}{\text{Molar mass of Carbon}}=\frac{49.48g}{12g/mole}=4.12moles

Moles of Hydrogen = \frac{\text{Given mass of Hydrogen}}{\text{Molar mass of Hydrogen}}=\frac{5.19g}{1g/mole}=5.19moles

Moles of Nitrogen = \frac{\text{Given mass of nitrogen}}{\text{Molar mass of nitrogen}}=\frac{28.85g}{14g/mole}=2.06moles

Moles of Oxygen = \frac{\text{Given mass of oxygen}}{\text{Molar mass of oxygen}}=\frac{16.48g}{16g/mole}=1.03moles

Step 2: Calculating the mole ratio of the given elements.

For the mole ratio, we divide each value of the moles by the smallest number of moles calculated which is 1.03 moles.

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For Nitrogen = \frac{2.06}{1.03}=2

For Nitrogen = \frac{1.03}{1.03}=1

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The ratio of C : H : N : O = 4 : 5 : 2 : 1

The empirical formula for the given compound is C_4H_5N_2O_1=C_4H_5N_2O

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