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tekilochka [14]
2 years ago
10

At a certain temperature the vapor pressure of pure acetyl bromide is measured to be . Suppose a solution is prepared by mixing

of acetyl bromide and of heptane . Calculate the partial pressure of acetyl bromide vapor above this solution. Round your answer to significant digits. Note for advanced students: you may assume the solution is ideal.
Chemistry
1 answer:
Rudik [331]2 years ago
8 0

Answer:

0.17 atm

Explanation:

Raoult´s law can be applied in solving this problem:

Pa= XaPºa   (a= acetyl bromide in this case)

where Pa = partial pressure acetyl bromide

         Xa = mole fraction of acetyl bromide in the solution

          Pºa=  vapor pressure of pure acetyl bromide = 0.75 atm(given)

Hence we can find the mole fraction of the acetone in the mixture:

Let the number of moles of acetone be a and the number of moles of thiophene be t

Xa = mol of a / ( mol of a + mol of t )        

We now have;

Molar Weight of  a= 112.95 g/mol  

number of moles of a = 51.8 g/mol x 1 mol/122.95 g  =  0.42 moles

Molar Weight of t = 84.14 g/mol  

number of moles of  t = 123 g x  1mol/84.14 g= 1.46 mol

mole fraction of a; Xa = 0.42/ (0.42 + 1.46) = 0.22

Pa = 0.22 x 0.75 atm = 0.17 atm

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2.1K viewsView 2 Upvoters

2



1

Related Questions (More Answers Below)
8 0
2 years ago
Draw the alkene formed when 1-heptyne is treated with hbr in the presence of peroxide.
Nimfa-mama [501]
<h2>Heptene formed is -</h2><h2>CH_3-CH_2-CH_2-CH_2-CH_2-CH=CHBr</h2>

Explanation:

The two possibilities when the peroxide is not present

  • CH_{3}-CH_{2}-CH_{2}-CH_{2}-CH_{2}-C≡CH +HBr → CH_3-CH_2-CH_2-CH_2-CH_2-CBr=CH_{2}

  • CH_3-CH_2-CH_2-CH_2-CH_2-CBr=CH_2 + HBr →CH_3-CH_2-CH_2-CH_2-CH_2-CBr_2-CH_3

In presence peroxide,

CH_3-CH_2-CH_2-CH_2-CH_2-C≡CH+ HBr →CH_3-CH_2-CH_2-CH_2-CH_2-CH=CHBr

  • When peroxides are present in the reaction mixture, hydrogen bromide adds to the triple bond of heptane with regioselectivity.
  • This reaction is opposite to that of Markovnikov's rule which says that when asymmetrical alkene reacts with a protic acid HX, then the hydrogen of an acid is attached to the carbon with more in number of hydrogen substituents, and the halide (X) group is attached to the carbon with more in number of substituents of alkyl.
  • One mole of HBr adds to one mole of 1-heptane.
  • The structure of heptene formed is -

CH_3-CH_2-CH_2-CH_2-CH_2-CH=CHBr

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Answer: See attached image

Explanation:

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