To evaluate the accuracy of a measurement, the measured value must be compared to the correct value. To evaluate the precision of a measurement, you must compare the values of two or more repeated measurements.
Answer:
The molar concentration of this solution is 0.0463 mol/L
Explanation:
Step 1 : Data given
Mass of a nonelectrolyte solute = 2.69 grams
Volume of water = 345 mL = 0.345 L
Temperature = 26.0°CC = 273 + 26 = 299 K
The osmotic pressure = 863 torr
⇒ 863torr /760 = 1.13553 atm
Step 2: Calculate the molar concentration of this solution
Π = i*M*R*T
⇒with Π = the osmotic pressure = 1.13553 atm
⇒with i = the van't Hoff factor of the nonelectrolyte solute = 1
⇒with M = the molar concentration = TO BE DETERMINED
⇒with R = the gas constant = 0.08206 L*atm/mol*K
⇒with T = the temperature = 299 K
1.13553 atm = 1 * M * 0.08206 L*atm/mol*K * 299 K
M = 1.13553 / (0.08206*299)
M = 0.0463 mol/L
The molar concentration of this solution is 0.0463 mol/L
Constant Volume Calorimetry, also know as bomb calorimetry, is used to measure the heat of a reaction while holding volume constant and resisting large amounts of pressure. Although these two aspects of bomb calorimetry make for accurate results, they also contribute to the difficulty of bomb calorimetry. In this module, the basic assembly of a bomb calorimeter will be addressed, as well as how bomb calorimetry relates to the heat of reaction and heat capacity and the calculations involved in regards to these two topics.
Introduction
Calorimetry is used to measure quantities of heat, and can be used to determine the heat of a reaction through experiments. Usually a coffee-cup calorimeter is used since it is simpler than a bomb calorimeter, but to measure the heat evolved in a combustion reaction, constant volume or bomb calorimetry is ideal. A constant volume calorimeter is also more accurate than a coffee-cup calorimeter, but it is more difficult to use since it requires a well-built reaction container that is able to withstand large amounts of pressure changes that happen in many chemical reactions.
Most serious calorimetry carried out in research laboratories involves the determination of heats of combustion ΔHcombustion" role="presentation" style="display: inline-table; font-style: normal; font-weight: normal; line-height: normal; font-size: 14.4px; text-indent: 0px; text-align: left; text-transform: none; letter-spacing: normal; word-spacing: normal; word-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; padding: 0px; margin: 0px; position: relative;">ΔHcombustionΔHcombustion, since these are essential to the determination of standard enthalpies of formation of the thousands of new compounds that are prepared and characterized each month. In a constant volume calorimeter, the system is sealed or isolated from its surroundings, and this accounts for why its volume is fixed and there is no volume-pressure work done. A bomb calorimeter structure consists of the following:
Steel bomb which contains the reactantsWater bath in which the bomb is submergedThermometerA motorized stirrerWire for ignition
is usually called a “bomb”, and the technique is known as bomb calorimetry
Another consequence of the constant-volume condition is that the heat released corresponds to qv , and thus to the internal energy change ΔUrather than to ΔH. The enthalpy change is calculated according to the formula
(1.1)ΔH=qv+ΔngRT" role="presentation" style="display: inline-table; font-style: normal; font-weight: normal; line-height: normal; font-size: 14.4px; text-indent: 0px; text-align: center; text-transform: none; letter-spacing: normal; word-spacing: normal; word-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; padding: 0px; margin: 0px; width: 10000em !important; position: relative;">ΔH=qv+ΔngRT(1.1)(1.1)ΔH=qv+ΔngRT
Δng" role="presentation" style="display: inline-table; font-style: normal; font-weight: normal; line-height: normal; font-size: 14.4px; text-indent: 0px; text-align: left; text-transform: none; letter-spacing: normal; word-spacing: normal; word-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; padding: 0px; margin: 0px; position: relative;">ΔngΔng is the change in the number of moles of gases in the reaction.
Answer:
electron-electron repulsion
Explanation:
When electrons add into valence shell of neutral elements, the element assumes a negative oxidation state. With this, the number of electrons having (-) charges will be larger than the number of protons having positive (+) charges. As a result, the extra electrons repel one another (i.e., like charges repel) and a larger radius is the result.
In contrast, when cations are formed, electrons are removed from the valence level (oxidation) producing an element having a greater number of protons than electrons. The larger number of protons will function to attract the electron cloud with a greater force that results in a contraction of atomic radius and a smaller spherical volume than the neutral unionized element.
To visualize, see attached chart that shows atomic and ionic radii before and after ionization of the elements.
