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Svet_ta [14]
4 years ago
7

10.0 g Cu, C Cu = 0.385 J/g°C 10.0 g Al, C Al = 0.903 J/g°C 10.0 g ethanol, Methanol = 2.42 J/g°C 10.0 g H2O, CH2O = 4.18 J/g°C

10.0 g Pb C Pb = 0.128 J/g°C Which of the following substances (with specific heat capacity provided) would show the greatest temperature change upon absorbing 100.0 J of heat
Chemistry
1 answer:
Mazyrski [523]4 years ago
3 0

Answer:

Lead shows the greatest temperature change upon absorbing 100.0 J of heat.

Explanation:

Q=mc\Delte T

Q = Energy gained or lost by the substance

m = mass of the substance

c = specific heat of the substance

ΔT = change in temperature

1) 10.0 g of copper

Q = 100.0 J (positive means that heat is gained)

m = 10.0 g

Specific heat of the copper = c =  0.385 J/g°C

\Delta T=\frac{Q}{mc}

=\frac{100.0 J}{10 g\times 0.385J/g^oC}=25.97^oC

2) 10.0 g of aluminium

Q = 100.0 J (positive means that heat is gained)

m = 10.0 g

Specific heat of the aluminium= c =  0.903 J/g°C

\Delta T=\frac{Q}{mc}

=\frac{100.0 J}{10 g\times 0.903 J/g^oC}=11.07^oC

3) 10.0 g of ethanol

Q = 100.0 J (positive means that heat is gained)

m = 10.0 g

Specific heat of the ethanol= c =  2.42 J/g°C

\Delta T=\frac{Q}{mc}

=\frac{100.0 J}{10 g\times 2.42 J/g^oC}=4.13 ^oC

4) 10.0 g of water

Q = 100.0 J (positive means that heat is gained)

m = 10.0 g

Specific heat of the water = c =  4.18J/g°C

\Delta T=\frac{Q}{mc}

=\frac{100.0 J}{10 g\times 4.18 J/g^oC}=2.39 ^oC

5) 10.0 g of lead

Q = 100.0 J (positive means that heat is gained)

m = 10.0 g

Specific heat of the lead= c =  0.128 J/g°C

\Delta T=\frac{Q}{mc}

=\frac{100.0 J}{10 g\times 0.128 J/g^oC}=78.125^oC

Lead shows the greatest temperature change upon absorbing 100.0 J of heat.

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c. pH = 2.83

Explanation:

a. Based in the chemical equation:

C₆H₅NH₂(aq) + HCl(aq) → C₆H₅NH₃⁺(aq) + Cl⁻(aq)

<em>1 mole of aniline reacts per mole of HCl</em>

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As the original solution had a volume of 25.0mL = 0.0250L:

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But now, volume is 25.0mL + 25.67mL = 50.67mL = 0.05067L. Thus, molar concentration of C₆H₅NH₃⁺ is:

[C₆H₅NH₃⁺] = 4.492x10⁻³ moles / 0.05067L = 0.0887M C₆H₅NH₃⁺

c. At equivalence point you have just 0.0887M C₆H₅NH₃⁺ in solution. C₆H₅NH₃⁺ has as equilibrium in water:

C₆H₅NH₃⁺(aq) + H₂O(l) → C₆H₅NH₂ + H₃O⁺

Where Ka = Kw / Kb = 1x10⁻¹⁴ / 4.0x10⁻¹⁰ =

<em>2.5x10⁻⁵ = [C₆H₅NH₂] [H₃O⁺] / [C₆H₅NH₃⁺]</em>

When the system reaches equilibrium, molar concentrations are:

[C₆H₅NH₃⁺] = 0.0887M - X

[C₆H₅NH₂] = X

[H₃O⁺] = X

Replacing in Ka formula:

2.5x10⁻⁵ = [X] [X] / [0.0887M - X]

2.2175x10⁻⁶ - 2.5x10⁻⁵X = X²

0 = X² + 2.5x10⁻⁵X - 2.2175x10⁻⁶

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X = -0.0015 → False solution. There is no negative concentrations.

X = 0.001477 → Right solution.

As [H₃O⁺] = X, [H₃O⁺] = 0.001477

Knowing pH = -log [H₃O⁺]

pH = -log 0.001477

<h3>pH = 2.83</h3>

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