Answer:
CH₃CH₂CH₂COOH > CH₃CH₂COOH > ClCH₂CH₂COOH > ClCH₂COOH
Explanation:
Electron-withdrawing groups (EWGs) increase acidity by inductive removal of electrons from the carboxyl group.
Electron-donating groups (EDGs) decrease acidity by inductive donation of electrons to the carboxyl group.
- The closer the substituent is to the carboxyl group, the greater is its effect.
- The more substituents, the greater the effect.
- The effect tails off rapidly and is almost zero after about three C-C bonds.
CH₃CH₂-CH₂COOH — EDG — weakest — pKₐ = 4.82
CH₃-CH₂COOH — reference — pKₐ = 4.75
ClCH₂-CH₂COOH — EWG on β-carbon— stronger — pKₐ = 4.00
ClCH₂COOH — EWG on α-carbon — strongest — pKₐ = 2.87
Number of electron pairs = \frac{1}{2}[V+N-C+A]
2
1
[V+N−C+A]
V = number of valence electrons present in central atom
N = number of monovalent atoms bonded to central atom
C = charge of cation
A = charge of anion
SbCl_5SbCl
5
:
In the given molecule, antimony is the central atom and there are five chlorine as monovalent atoms.
The number of electron pairs are 5 that means the hybridization will be sp^3dsp
3
B and geometry of the molecule will be trigonal bipyramidal.
Answer:
Balanced reaction:
3 H2 (g) + N2 (g) → 2 NH3 (g)
Use stoichiometry to convert g of H2 to g of NH3. The process would be:
g H2 → mol H2 → mol NH3 → g NH3
12.0 g H2 x (1 mol H2 / 2.02 g H2) x (2 mol NH3 / 3 mol H2) x (17.03 g NH3 / 1 mol NH3) = 67.4 g NH3
Explanation: See above
Hope this helps, friend.
Answer:
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