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gayaneshka [121]
3 years ago
13

What is the freezing point of a solution of 0.5 mol of LiBr in 500 mL of water? (Kf = 1.86°C/m) –1.86°C –7.44°C –5.58°C –3.72°C

Chemistry
1 answer:
tresset_1 [31]3 years ago
6 0

Answer:

  • Last choice: <em><u>- 3.72°C</u></em>

Explanation:

The freezing point depression in a solvent is a colligative property: it depends on the number of solute particles.

The equation to predict the freezing point depression in a solvent is:

  • ΔTf = Kf × m × i

Where,

  • ΔTf is the freezing point depression of the solvent,
  • m is the molality,
  • Kf is the cryoscopic molal constant of the solvent, and i is the Van'f Hoff factor, which is the number of ions produced by each unit formula of the ionic compound.

The calcualtions are in the attached pdf file. Please, open it by clicking on the image of the file.

Download pdf
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0.5 gm of mixture of NH4Cl and NaCl was boiled with 25 ml of 0.95 N NaOH in a vessel till all the ammonia is expelled.The residu
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Answer:

72.66%

Explanation:

NH₄Cl reacts in presence of NaOH producing ammonia, NH₃, as follows:

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The residual NaOH reacts with H₂SO₄ as follows:

2NaOH + H₂SO₄ → Na₂SO₄ + 2H₂O.

The equivalent-gram of H₂SO₄ are:

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As the complete residual solution is 100mL but the neutralization was made only with 10mL, the mEq you need to neutralize the residual NaOH is:

1.696mEq * (100mL / 10mL) = 16.96mEq.

The mEq of NaOH you add in the first are:

25mL * 0.95mEq = 23.75mEq

That means the NaOH that reacts = moles of NH₄Cl is:

23.75mEq - 16.96mEq = 6.79mEq = 6.79mmoles NH₄Cl =

6.79x10⁻³ moles NH₄Cl

In grams (Using molar mass NH₄Cl = 53.5g/mol):

6.79x10⁻³ moles NH₄Cl * (53.5g / mol) =

0.3633g of NH₄Cl are in the original mixture.

% is:

0.3633g/ 0.5g * 100 = 72.66%

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what is the empirical formula of a compound if a sample contains 8.52g of carbon and 1.43 grams of hydrogen?
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