The correct answer is a. This is because the pH of a solution is defined as -log10(concentration of H+ ions). An inverse logarithmic scale such as this means that a solution with a lower concentration of H+ ions will have a higher pH than one with a higher concentration. Therefore we know that the pH of the second sample will be higher than the first.
Since the logarithmic scale has the base 10, a change by 1 on the scale is a consequence of multiplication/division of the H+ concentration by a factor of 10. As the scale is inverse, this means that a decrease of concentration by factor 1000 is equivalent to increasing the pH by (1000/10) = 3.
For an aqueous solution of MgBr2, a freezing point depression occurs due to the rules of colligative properties. Since MgBr2 is an ionic compound, it acts a strong electrolyte; thus, dissociating completely in an aqueous solution. For the equation:
ΔTf<span> = (K</span>f)(<span>m)(i)
</span>where:
ΔTf = change in freezing point = (Ti - Tf)
Ti = freezing point of pure water = 0 celsius
Tf = freezing point of water with solute = ?
Kf = freezing point depression constant = 1.86 celsius-kg/mole (for water)
m = molality of solution (mol solute/kg solvent) = ?
i = ions in solution = 3
Computing for molality:
Molar mass of MgBr2 = 184.113 g/mol
m = 10.5g MgBr2 / 184.113/ 0.2 kg water = 0.285 mol/kg
For the problem,
ΔTf = (Kf)(m)(i) = 1.86(0.285)(3) = 1.59 = Ti - Tf = 0 - Tf
Tf = -1.59 celsius
The smallest halogen atom is fluorine
Gasoline would be a mixture if I recalled
M CH₃COOH: 12u×2 + 1u×4 + 16u×2 =<u> 60u</u>
m 9CH₃COOH: 60u×9 = <u>540u</u>
<em>(1u ≈ 1,66·10⁻²⁴g)</em>
-----------------------------
1u ------- <span>1,66·10⁻²⁴g
540u ---- X
X = 540</span>×<span>1,66·10⁻²⁴g
<u>X = 896,4</u></span><span><u>·10⁻²⁴g
</u></span>