Answer:
n = 0.207 mole
Explanation:
We have,
P = 1 atm
V = 5 liter
R = 0.0821 L.atm/mol.K
T = 293 K
We need to find the value of n. The relation is as follows :
PV = nRT
Solving for n,
So, the value of n is 0.207 mol.
O B. The total mass of the reactants equals the total mass of the
products.
Alkenes on reaction with meta-chloroperoxybenzoic acid (MCPBA ) produces epoxides. When styrene is reacted with mCPBA it gives 2-phenyloxirane as shown below,
First, we have to get:
1- The heat required to increase T of ice from -50 to 0 °C:
according to q formula:
q1 = m*C*ΔT
when m is the mass of ice = mol * molar mass
= 1 mol * 18 mol/g
= 18 g
and C is the specific heat capacity of ice = 2.09 J/g-K
and ΔT change in temperature = 0- (-50) = 50°C
by substitution:
∴q1 = 18 g * 2.09 J/g-K *50°C
= 1881 J = 1.881 KJ
2- the heat required to melt this mass of ice is :
q2 = n*ΔHfus
when n is the number of moles of ice = 1 mol
and ΔHfus = 6.01 KJ/mol
by substitution:
q2 = 1 mol * 6.01 KJ/mol
= 6.01 KJ
3- the heat required to increase the water temperature from 0°C to 60 °C is:
q3 = m*C*ΔT
when m is the mass of water = 18 g
C is the specific heat capacity of water = 4.18 J/g-K
ΔT is the change of Temperature of water = 60°C - 0°C = 60°C
by substitution:
∴q3 = 18 g * 4.18 J/g-K * 60°C
= 4514 J = 4.514 KJ
∴the total change of enthalpy = q1+q2+q3
= 1.881 KJ +6.01 KJ + 4.514 KJ
= 12.405 KJ
