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Ad libitum [116K]
3 years ago
9

For the following SN1 solvolysis reaction, select the correct rate equation and the overall reaction order (note: CH3OH is the s

olvent for the reaction). (CH3)3CCl + CH3OH → (CH3)3OCH3 + HCl
Chemistry
1 answer:
sineoko [7]3 years ago
8 0

Answer:

Explanation:

  • rate = K[(CH3)3CCl]
  • overall order is also first order

Since we are told that CH3OH is the solvent for the reaction, as such the rate law equation will only be written for (CH3)3CCl .

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Pressure gauge at the top of a vertical oil well registers 140 bars. The oil well is 6000 m deep and filled with natural gas dow
andreyandreev [35.5K]

Explanation:

(a)  The given data is as follows.

              Pressure on top (P_{o}) = 140 bar = 1.4 \times 10^{7} Pa       (as 1 bar = 10^{5})

              Temperature = 15^{o}C = (15 + 273) K = 288 K

         Density of gas = \frac{PM}{ZRT}

                \frac{dP}{dZ} = \rho \times g

               \frac{dP}{dZ} = \int \frac{PM}{ZRT}

                \int_{P_{o}}^{P_{1}} \frac{dP}{dZ} = \frac{Mg}{ZRT} \int_{0}^{4700} dZ

           ln (\frac{P_{1}}{P_{o}}) = \frac{18.9 \times 10^{-3} \times 9.81 \times 4700 m}{0.80 \times 8.314 J/mol K \times 288 K}

                              = 0.4548

                     P_{1} = P_{o} \times e^{0.4548}

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                                 = 2.206 \times 10^{7} Pa

Hence, pressure at the natural gas-oil interface is 2.206 \times 10^{7} Pa.

(b)   At the bottom of the tank,

                 P_{2} = P_{1}  + \rho \times g \times h

                             = 2.206 \times 10^{7} Pa + 700 \times 9.81 \times (6000 - 4700)[/tex]

                             = 309.8 \times 10^{5} Pa

                             = 309.8 bar

Hence, at the bottom of the well at 15^{o}C pressure is 309.8 bar.

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