Answer : The correct option is, +91 kJ/mole
Solution :
The balanced cell reaction will be,

Here copper (Cu) undergoes oxidation by loss of electrons, thus act as anode. Lead (Pb) undergoes reduction by gain of electrons and thus act as cathode.
First we have to calculate the standard electrode potential of the cell.
![E^0_{[Pb^{2+}/Pb]}=-0.13V](https://tex.z-dn.net/?f=E%5E0_%7B%5BPb%5E%7B2%2B%7D%2FPb%5D%7D%3D-0.13V)
![E^0_{[Cu^{2+}/Cu]}=+0.34V](https://tex.z-dn.net/?f=E%5E0_%7B%5BCu%5E%7B2%2B%7D%2FCu%5D%7D%3D%2B0.34V)

![E^0_{cell}=E^0_{[Pb^{2+}/Pb]}-E^0_{[Cu^{2+}/Cu]}](https://tex.z-dn.net/?f=E%5E0_%7Bcell%7D%3DE%5E0_%7B%5BPb%5E%7B2%2B%7D%2FPb%5D%7D-E%5E0_%7B%5BCu%5E%7B2%2B%7D%2FCu%5D%7D)

Now we have to calculate the standard Gibbs free energy.
Formula used :

where,
= standard Gibbs free energy = ?
n = number of electrons = 2
F = Faraday constant = 96500 C/mole
= standard e.m.f of cell = -0.47 V
Now put all the given values in this formula, we get the Gibbs free energy.

Therefore, the standard Gibbs free energy is +91 kJ/mole
It should be noted that when Brian first sorted out his thoughts, the first thing that he thought would happen next is that he would probably be rescued that day.
It should be noted that in Chapter 5 of Hatchet, Brian wakes up in the forest and then, he realized that he was desperately thirsty.
When Brian first sorted out his thoughts, he figured this was the first day after the crash and that he would probably be rescued that day. He believed that he was going to wither up and die if he doesn't get anything that he'll drink.
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Do it urself ;) jdhdhdhdhdhhdhdhdhdhdhdhdhdhgdhd
By using the quantum model of the atom and John Dalton's model you can predict that the methane molecule will most likely be made up of Hydrogen and Carbon.