Guy-Lussac's Law states that the volume and the temperature are directly proportional given that the pressure remains constant.
For this problem, we will assume constant pressure. Based on the law:
(Volume/Temperatur)1 = (Volume/Temperature)2
(3.75/100) = (6.52/T)
T = 166.667 kelvin
Its b Fe(s) <span> Fe</span>2+(aq) + 2e– <span><span> </span>E</span><span> = </span><span>+0.44 V</span>
Answer:
Change in entropy for the reaction is
ΔS° = -268.13 J/K.mol
Explanation:
To calculate the change in entropy for the balanced reaction, we require the natural entropy of all the reactants and products in the reaction.
3 NO₂(g) + H₂O(l) → 2 HNO₃(l) + NO(g)
From Literature.
S°(NO₂) = 240.06 J/K.mol
S°(H₂O) = 69.91 J/K.mol
S°(HNO₃) = 155.60 J/K.mol
S°(NO) = 210.76 J/K.mol
These are the entropies of the reactants and products under standard conditions of 298.15 K and 1 atm.
Note that
ΔS° = Σ nᵢS°(for products) - Σ nᵢS°(for reactants)
Σ nᵢS°(for products) = [2 × S°(HNO₃)] + [1 × S°(NO)]
= (2 × 155.60) + (1 × 210.76) = 521.96 J/K.mol
Σ nᵢS°(for reactants) = [3 × S°(NO₂)] + [1 × S°(H₂O)]
= (3 × 240.06) + (1 × 69.91) =790.09 J/K.mol
ΔS° = Σ nᵢS°(for products) - Σ nᵢS°(for reactants)
ΔS° = 521.96 - 790.09 = -268.13 J/K.mol
Hope this Helps!!
Here we apply the Clausius-Clapeyron equation:
ln(P₁/P₂) = ΔH/R x (1/T₂ - 1/T₁)
The normal vapor pressure is 4.24 kPa (P₁)
The boiling point at this pressure is 293 K (P₂)
The heat of vaporization is 39.9 kJ/mol (ΔH)
We need to find the vapor pressure (P₂) at the given temperature 355.3 K (T₂)
ln(4.24/P₂) = 39.9/0.008314 x (1/355.3 - 1/293)
P₂ = 101.2 kPa