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Semenov [28]
3 years ago
12

When the following redox equation is balanced with smallest whole number coefficients, the coefficient for the iodide ion will b

e _____.
I–(aq) + NO3–(aq) → NO(g) + I2(s) (acidic solution)
Chemistry
1 answer:
Vikentia [17]3 years ago
7 0

Answer:

When the following redox equation is balanced with smallest whole number coefficients, the coefficient for the iodide ion will be __6__.

Explanation:

From the redox equation, we can see that NO₃⁻ is reduced to NO (from oxidation state +5 to +2), whereas I⁻ is oxidized to I₂ (from oxidation state -1 to 0). The half reactions are balanced with H⁺ (acidic solution), as follows:

Reduction :        2 x (NO₃⁻(aq) + 3 e-  + 4 H⁺ → NO(g) + 2 H₂O)

Oxidation :                                   3 x (2 I⁻(aq) → I₂(s) + 2 e-)

                       ----------------------------------------------------------------------

Total equation: 6 I⁻(aq) + 2 NO₃⁻(aq)+ 8 H⁺ → 3 I₂(s) + 2 NO(g) + 4 H₂O

That is the redox equation with the smallest whole number coefficients.

Accordin to this, the coefficient for the iodide ion (I⁻) is: 6.

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a=\left [\frac{2atoms/\text{unit cell}\left (\frac{100}{\frac{85\%}{55.85g/mol}+\frac{15\%}{50.941g/mol}}  \right )}{(6.023\times10^{23}atoms/mol)\left (\frac{100}{\frac{85\%}{7.874g/cm^3}+\frac{15\%}{6.10g/cm^3}}  \right )}  \right ]^{1/3}

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