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rjkz [21]
3 years ago
6

What is the energy of light associated with a transition from n=3 to n=8 in a hydrogen atom? Does this represent absorption or e

mission of a photon?
Chemistry
1 answer:
solong [7]3 years ago
8 0

Explanation:

Energy levels to be n = 8 and n = 3. Rydberg's equation will allow you calculate the wavelength of the photon emitted by the electron during this transition

1λ = R ⋅ (1/nf^2 − 1/ni^2)

where,

λ - the wavelength of the emitted photon

R - Rydberg's constant = 1.0974 x 10^7m

nf - the final energy = 8

ni - the initial energy level = 3

1/λ = 1.0974 x 10^7 * (1/8^2 − 1/3^2)

= -1.05x 10^6 m.

Using Heinsberg's equation,

E = (h * c)/λ

Calculating the energy of this transition you'll have to multiply Rydberg's equation by h * c

where,

h - Planck's constant = 6.626 x 10^−34 Js

c - the speed of light = 3.0 x 10^8 m/s

So, the transition energy, E = (6.626 x 10^−34 * 3 x 10^8) * -1.05x 10^6

= -2.08 x 10^-19 J.

B.

When an electron transitions from a less excited state to a excited state (higher energy orbit), the difference in energy is absorbed as a photon.

The energy is negative which means energy is lost or dissipated to the surroundings. Therefore, an absorption of photons.

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Dissolution of KOH, ΔHsoln:
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Using Hess's law we found:

1) By <em>adding </em>reaction 10.2 with the <em>reverse </em>of reaction 10.1 we get reaction 10.3:

KOH(aq) + HCl(aq)  → H₂O(l) + KCl(aq)   ΔH  (10.3)

2) The ΔHsoln must be subtracted from ΔHneut to get the <em>total </em>change in enthalpy (ΔH).    

The reactions of dissolution (10.1) and neutralization (10.2) are:

KOH(s) → KOH(aq)   ΔHsoln    (10.1)

KOH(s) + HCl(aq) → H₂O(l) + KCl(aq)     ΔHneut     (10.2)

1) According to Hess's law, the total change in enthalpy of a reaction resulting from <u>differents changes</u> in various <em>reactions </em>can be calculated as the <u>sum</u> of all the <em>enthalpies</em> of all those <em>reactions</em>.      

Hence, to get reaction 10.3:

KOH(aq) + HCl(aq) → H₂O(l) + KCl(aq)    (10.3)

We need to <em>add </em>reaction 10.2 to the <u>reverse</u> of reaction 10.1

KOH(s) + HCl(aq) + KOH(aq) → H₂O(l) + KCl(aq) + KOH(s)

<u>Canceling</u> the KOH(s) from both sides, we get <em>reaction 10.3</em>:

KOH(aq) + HCl(aq)  → H₂O(l) + KCl(aq)    (10.3)

2) The change in enthalpy for <em>reaction 10.3</em> can be calculated as the sum of the enthalpies ΔHsoln and ΔHneut:

\Delta H = \Delta H_{soln} + \Delta H_{neut}

The enthalpy of <em>reaction 10.1 </em>(ΔHsoln) changed its sign when we reversed reaction 10.1, so:

\Delta H = \Delta H_{neut} - \Delta H_{soln}

Therefore, the ΔHsoln must be <u>subtracted</u> from ΔHneut to get the total change in enthalpy ΔH.

Learn more here:

  • brainly.com/question/2082986?referrer=searchResults
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I hope it helps you!

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