Answer: The most likely partial pressures are 98.7MPa for NO₂ and 101.3MPa for N₂O₄
Explanation: To determine the partial pressures of each gas after the increase of pressure, it can be used the equilibrium constant Kp.
For the reaction 2NO₂ ⇄ N₂O₄, the equilibrium constant is:
Kp = 
where:
P(N₂O₄) and P(NO₂) are the partial pressure of each gas.
Calculating constant:
Kp = 
Kp = 0.0104
After the weights, the total pressure increase to 200 MPa. However, at equilibrium, the constant is the same.
P(N₂O₄) + P(NO₂) = 200
P(N₂O₄) = 200 - P(NO₂)
Kp =
0.0104 = ![\frac{200 - P(NO_{2}) }{[P(NO_{2} )]^{2}}](https://tex.z-dn.net/?f=%5Cfrac%7B200%20-%20P%28NO_%7B2%7D%29%20%20%7D%7B%5BP%28NO_%7B2%7D%20%29%5D%5E%7B2%7D%7D)
0.0104![[P(NO_{2} )]^{2}](https://tex.z-dn.net/?f=%5BP%28NO_%7B2%7D%20%29%5D%5E%7B2%7D)
+ 
- 200 = 0
Resolving the second degree equation:
= 
= 98.7
Find partial pressure of N₂O₄:
P(N₂O₄) = 200 - P(NO₂)
P(N₂O₄) = 200 - 98.7
P(N₂O₄) = 101.3
The partial pressures are = 98.7 MPa and P(N₂O₄) = 101.3 MPa
Reactant molecules are any substance that goes into a reaction. When forming product molecules, the reactant molecules combine and create a new molecule (i.e. the combination of methane and oxygen can make carbon dioxide and water).
Chloride ions Cl –(aq) (from the dissolved sodium chloride) are discharged at the positive electrode as chlorine gas, Cl 2(g) sodium ions Na +(aq) (from the dissolved sodium chloride) and hydroxide ions OH –(aq) (from the water) stay behind - they form sodium hydroxide solution, NaOH(aq)
Answer:
They decrease, because of the stronger effective nuclear charge.
Explanation:
- Atomic radii decreases from left to right across a period.
- This is due to the increase in the no. of protons and electrons through the period.
- One proton has a greater effect than one electron.
- So, electrons are attracted towards the nucleus and resulting in a smaller atomic radii.
<em>Thus, the right choice is: They decrease, because of the stronger effective nuclear charge.</em>
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