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Shalnov [3]
4 years ago
5

A sample of neon occupies a volume of 752 ml at 25 0

Chemistry
1 answer:
lyudmila [28]4 years ago
5 0
V_{initial} = 752\:mL
T_{initial} = 25.0^0C
converting to Kelvin
TK = TC + 273
TK = 25.0 + 273 → TK = 298.0 → T_{initial} = 298.0\:K
V_{final} = ? (in\:milliliters)
T_{final} = 50.0^0C
TK = TC + 273
TK = 50.0 + 273 → TK = 323.0 → T_{final} = 323.0\:K

By the first Law of Charles and Gay-Lussac, we have: 
\frac{ V_{i} }{ T_{i} } = \frac{ V_{f} }{ T_{f} }

Solving:
\frac{ V_{i} }{ T_{i} } = \frac{ V_{f} }{ T_{f} }
\frac{ 752 }{ 298.0 } = \frac{ V_{f} }{ 323.0 }
Product of extremes equals product of means:
298.0* V_{f} = 752*323.0
298.0 V_{f} = 242896
V_{f} = \frac{242896}{298.0}
\boxed{\boxed{V_{f} \approx 815.08\:mL}}\end{array}}\qquad\quad\checkmark
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The lab just ran out of 1 M HCl that you need to complete the Benzillic Acid lab. The TA tells you there is 12 M HCl in the fume
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Answer:

0.83 mL

Explanation:

Given data

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We can calculate the initial volume of HCl using the dilution rule.

C₁ × V₁ = C₂ × V₂

V₁ = C₂ × V₂ / C₁

V₁ = 1.0 M × 10.0 mL / 12 M

V₁ = 0.83 mL

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gavmur [86]
There are a number of ways to reduce friction:

Make the surfaces smoother. Rough surfaces produce more friction and smooth surfaces reduce friction. Some swimmers wear suits to reduce underwater resistance. These suits mimic the smooth skin of sharks.

Lubrication is another way to make a surface smoother. A lubricant is a slippery substance designed to reduce the friction between surfaces. You might use oil to stop a door from squeaking - the oil reduces the friction in the hinge. Water can be used as a lubricant - think of how a floor becomes slippery after it has been mopped.

Make the object more streamlined. A streamline shape is one that allows air or water to flow around it easily, offering the least resistance. Compare a boxy old car with a new car that has a rounded shape, allowing it to move with less effort.

Reduce the forces acting on the surfaces. The stronger the forces acting on the surfaces, the higher the friction, so reducing the forces would reduce the friction. If you apply the handbrake when you try to drive a car, the car will have a lot of difficulty moving because of the force immobilising (stopping the movement of) the wheels. If you release the handbrake, the wheels will move more freely because there is no extra force acting on them.

Reduce the contact between the surfaces. Have you ever tried to roll a cube? Spheres are the best shape for reducing friction because very little of a spherical object is in contact with the other surface. Several types of wheels, such as skateboard wheels, contain small spheres called ball bearings to reduce the friction between the moving parts. You can witness the effect of ball bearings by comparing the friction between sliding a book on a table and then doing the same, but using marbles between the book and the surface of the table. Notice how the marbles act as ball bearings, reducing the friction.

8 0
4 years ago
A second- order reaction of the type A + B -->P was carried out in a solution that was initially 0.075 mol dm^-3 in A and 0.0
andriy [413]

Answer:

a) 16.2 dm^3/mol*h

b) 6.1 × 10^3 s, 2.5 × 10^3 s (it is different to the hint)

Explanation:

We can use the integrated rate equation in order to obtain k.

For the reaction A+ B --> P the reaction rate is written as

Rate = -\frac{dC_A}{dt} = -\frac{dC_B}{dt} = \frac{dC_P}{dt} = kC_AC_B

If C_{A0} and C_{B0} are the inital concentrations and x the concentration reacted at time t, so C_A=C_{A0} -x and C_B=C_{B0} -x and the rate at time t is written as:

-\frac{dx}{dt} =-k(C_{A0} -x)(C_{B0}-x)

Separating variables and integrating

\int\limits^x_0 {\frac{1}{(C_{A0}-x)(C_{B0}-x)} } \, dx = \int\limits^t_0 {k} \, dt

The integral in left side is solved by partial fractions, it can be used integral tables

\frac{1}{C_{B0}-C_{A0}}(ln\frac{C_{A0}}{C_{A0}-x}-ln\frac{C_{B0}}{C_{B0}-x}) =kt

Using logarithm properties (ln x - ln y = ln(x/y))

\frac{1}{C_{B0}-C_{A0}}(ln\frac{C_{A0}C_{B}}{C_{A}C_{B0}}) =kt

Using the given values k can be calculated. But the data seems inconsistent since if the concentration of A changes from 0.075 to 0.02 mol dm^-3 it implies that 0.055 mol dm^-3 of A have reacted after 1 h, so according to the reaction given the same quantity of B should react, and we only have a C_{B0} of 0.05 mol dm^-3.

Assuming that the concentration of B fall to 0.02 mol dm^-3 (and not the concentration the A). So we arrive to the answer given in the Hint.

So, the values given are t= 1, C_{A0}=0.075, C_{B0}=0.05, C_{B}=0.02, it implies that the quantity reacted, x, is 0.03 and C_{A}=0.075-x = 0.045. Then, the value of k would be

kt = \frac{1}{0.05-0.075}(ln\frac{0.075*0.02}{0.045*0.05})

k = 16.21 \frac{dm^3}{mol*1h}

b) the question b requires calculate the time when the concentration of the specie is half of the initial concentration.

For reactant A, It is solved with the same equation

\frac{1}{C_{B0}-C_{A0}}(ln\frac{C_{A0}C_{B}}{C_{A}C_{B0}}) =kt

but suppossing that C_A= C_{A0}/2=0.0375 so  C_B=C_{B0}- C_{A0}/2=0.0125, k=16.2 and the same initial concentrations. Replacing in the equation

t=\frac{1}{16.2(0.05-0.075)}(ln\frac{0.075*0.0125}{0.0375*0.05})

t=1.71 h = 1.71*3600 s = 6.1*10^3 s  

For reactant B, C_B= C_{B0}/2=0.025 so  C_A=C_{A0}- C_{B0}/2=0.05, k=16.2 and the same initial concentrations. Replacing in the equation

t=\frac{1}{16.2(0.05-0.075)}(ln\frac{0.075*0.025}{0.05*0.05})

t=0.71 h = 0.7*3600 s = 2.5*10^3 s  

Note: The procedure presented is correct, despite of the answer be something different to the given in the hint, I obtain that result if the k is 19.2... (maybe an error in calculation of given numbers)

3 0
3 years ago
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