The answer is boiling liquids I think
By use of combined gas law
P2= T2P1V1/V2
v1=5L
P1=540 torr
T1=25+273=298k
V2=15 L
T2=32+273=305 k
P2 is therefore=( 305k x 540 torr x5 L) /( 15L x 298)= 184.23 torr
For what exactly ? just for fun or for educational purposes?
Answer : The value of rate constant is, 
Explanation :
First we have to calculate the rate constant, we use the formula :
Expression for rate law for first order kinetics is given by:

where,
k = rate constant = ?
t = time passed by the sample = 20 min
a = let initial amount of the reactant = 100 g
a - x = amount left after decay process = 100 - 85 = 15 g
Now put all the given values in above equation, we get


Therefore, the value of rate constant is, 