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marishachu [46]
3 years ago
6

List the spectator ions in the following reaction.

Chemistry
1 answer:
Rudik [331]3 years ago
4 0

Answer:

2Na⁺ (aq) and 2OH⁻(aq)

Explanation:

Spectator ions:

Spectator ions are those ions which are same on both side of chemical reaction. These ions are same in the reactant side and product side. Their presence can not effect the chemical equilibrium that's why when we write the net ionic equation these ions are neglect or omitted.

Given ionic equation:

Ba⁺²(aq) + 2OH⁻(aq) + 2Na⁺ (aq) + CO²⁻₃(aq) → BaCO₃(s) + + 2Na⁺ (aq) + 2OH⁻(aq)

In given ionic equation by omitting the spectator ions i.e, 2Na⁺ (aq) and 2OH⁻(aq)  net ionic equation can be written as,

Net ionic equation:

Ba⁺²(aq) + CO²⁻₃(aq) → BaCO₃(s)

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The density of the liquid is 0.98 g/mL

<h3>What is density? </h3>

The density of a substance is defined as the mass of the subtance per unit volume of the substance. Mathematically, it can be expressed as:

Density = mass / volume

With the above formula, we can obtain the density of the liquid.

<h3>How to determine the density </h3>
  • Mass = 30.8 g
  • Volume = 31.5 mL
  • Density =?

Density = mass / volume

Density of liquid = 30.8 / 31.5

Density of liquid = 0.98 g/mL

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. Determine the standard free energy change, ɔ(G p for the formation of S2−(aq) given that the ɔ(G p for Ag+(aq) and Ag2S(s) are
olga nikolaevna [1]

<u>Answer:</u> The standard free energy change of formation of S^{2-}(aq.) is 92.094 kJ/mol

<u>Explanation:</u>

We are given:

K_{sp}\text{ of }Ag_2S=8\times 10^{-51}

Relation between standard Gibbs free energy and equilibrium constant follows:

\Delta G^o=-RT\ln K

where,

\Delta G^o = standard Gibbs free energy = ?

R = Gas constant = 8.314J/K mol

T = temperature = 25^oC=[273+25]K=298K

K = equilibrium constant or solubility product = 8\times 10^{-51}

Putting values in above equation, we get:

\Delta G^o=-(8.314J/K.mol)\times 298K\times \ln (8\times 10^{-51})\\\\\Delta G^o=285793.9J/mol=285.794kJ

For the given chemical equation:

Ag_2S(s)\rightleftharpoons 2Ag^+(aq.)+S^{2-}(aq.)

The equation used to calculate Gibbs free change is of a reaction is:  

\Delta G^o_{rxn}=\sum [n\times \Delta G^o_f_{(product)}]-\sum [n\times \Delta G^o_f_{(reactant)}]

The equation for the Gibbs free energy change of the above reaction is:

\Delta G^o_{rxn}=[(2\times \Delta G^o_f_{(Ag^+(aq.))})+(1\times \Delta G^o_f_{(S^{2-}(aq.))})]-[(1\times \Delta G^o_f_{(Ag_2S(s))})]

We are given:

\Delta G^o_f_{(Ag_2S(s))}=-39.5kJ/mol\\\Delta G^o_f_{(Ag^+(aq.))}=77.1kJ/mol\\\Delta G^o=285.794kJ

Putting values in above equation, we get:

285.794=[(2\times 77.1)+(1\times \Delta G^o_f_{(S^{2-}(aq.))})]-[(1\times (-39.5))]\\\\\Delta G^o_f_{(S^{2-}(aq.))=92.094J/mol

Hence, the standard free energy change of formation of S^{2-}(aq.) is 92.094 kJ/mol

8 0
3 years ago
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