<u>Answer:</u> The correct option is
<u>Explanation:</u>
A catalyst is defined as the chemical species that increases the reaction rate but does not participate in it and is left behind after the completion.
A homogeneous catalyst is one that is present in the same phase as the reactants and products.
A heterogeneous catalyst is one that is present in different phase as that of reactants and products.
For the given chemical reaction:

As all the reactants and products are in gaseous state so, the homogeneous catalyst must also be in the gaseous state only.
Hence, the correct option is 
Answer:
the Molar heat of Combustion of diphenylacetylene
= 
Explanation:
Given that:
mass of diphenylacetylene
= 0.5297 g
Molar Mass of diphenylacetylene
= 178.21 g/mol
Then number of moles of diphenylacetylene
= 
= 
= 0.002972 mol
By applying the law of calorimeter;
Heat liberated by 0.002972 mole of diphenylacetylene
= Heat absorbed by
+ Heat absorbed by the calorimeter
Heat liberated by 0.002972 mole of diphenylacetylene
= msΔT + cΔT
= 1369 g × 4.184 J g⁻¹°C⁻¹ × (26.05 - 22.95)°C + 916.9 J/°C (26.05 - 22.95)°C
= 17756.48 J + 2842.39 J
= 20598.87 J
Heat liberated by 0.002972 mole of diphenylacetylene
= 20598.87 J
Heat liberated by 1 mole of diphenylacetylene
will be = 
= 6930979.139 J/mol
= 6930.98 kJ/mol
Since heat is liberated ; Then, the Molar heat of Combustion of diphenylacetylene
= 
214.0560
+ 9.3456
=223.4016
<span>294400 cal
The heating of the water will have 3 phases
1. Melting of the ice, the temperature will remain constant at 0 degrees C
2. Heating of water to boiling, the temperature will rise
3. Boiling of water, temperature will remain constant at 100 degrees C
So, let's see how many cal are needed for each phase.
We start with 320 g of ice and 100 g of liquid, both at 0 degrees C. We can ignore the liquid and focus on the ice only. To convert from the solid to the liquid, we need to add the heat of fusion for each gram. So multiply the amount of ice we have by the heat of fusion.
80 cal/g * 320 g = 25600 cal
Now we have 320 g of ice that's been melted into water and the 100 g of water we started with, resulting in 320 + 100 = 420 g of water at 0 degrees C. We need to heat that water to 100 degrees C
420 * 100 = 42000 cal
Finally, we have 420 g of water at the boiling point. We now need to pump in an additional 540 cal/g to boil it all away.
420 g * 540 cal/g = 226800 cal
So the total number of cal used is
25600 cal + 42000 cal + 226800 cal = 294400 cal</span>