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Juliette [100K]
3 years ago
15

Which has the lowest freezing point? pure water 0.5 M ionic NaCl 0.5 M ionic CaCl2 0.5 M ionic AlCl3 0.5 M molecular C12H22O11

Chemistry
2 answers:
sladkih [1.3K]3 years ago
6 0
Calcium chloride because it makes three ions for every one compounds. Colligative properties are affected by moles of substance that disrupt the surface tension. Sodium chloride makes only two and molecular substances don't dissociate
VashaNatasha [74]3 years ago
6 0

Answer:

The correct answer is AlCl₃ 0.5 M

Explanation:

Freezing-point point depression is a colligative property and it is directly proportional to the number of particles in which the solute dissociates in solution:

ΔTf= Kf x m x i

Where ΔTf is the freezing-point depression (fusion temperature of pure solvent - fusion temperature of solvent in solution), Kf is the cryoscopic constant, m is the molality of solution and i is the van't Hoff factor. The van't Hoff factor indicates the number of particles in which the solute dissociates per individual solute molecule. As more the van't Hoff factor, more the freezing point depression, and lower the freezing point.

As all the solutes has the same concentration (0.5 M), the solution with the lowest freezing point will be  one whose solute dissociates into the largest amount of particles:

NaCl → Na⁺ + Cl⁻ ⇒ i= 2

CaCl₂→ Ca⁺ + 2 Cl⁻ ⇒ i= 3

AlCl₃→ Al³⁺ + 3 Cl⁻  ⇒  i= 4

C₁₂H₂₂O₁ ⇒ i= 1

Thus, the AlCl₃ 0.5 M solution will be the one with lowest freezing point.

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Which of the following bases is the STRONGEST? The base is followed by its Kb.A. C6H5NH2, 4.0 × 10-10 B. NH3, 1.76 × 10-5 C. CH3
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Answer:

(D) (CH3CH2)2NH

Explanation:

In order to decide which base is strongest we need to calculate its PKb

PKb = -log [Kb]

A large Kb value and small PKb value gives the strongest base

 Compound                   Kb                           PKb      

(A) C6H5NH2 -         4 x 10^-10                      9.349

(B) NH3                     1.76x 10^-5                    4.754

(C) CH3NH2              4.4x 10^-4                     3.357

(D) (CH3CH2)2NH   8.6x 10^-4                     3.066

(E) C5H5N                  1.7x10^-9                      8.77  

Clearly (CH3CH2)2NH is the strongest base.

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hen working with very large or very small numbers, scientists, mathematicians, and engineers often use scientific notation to express those quantities. Scientific notation uses exponential notation. The following are examples of scientific notation.

Light year: number of miles light travels in one year, about 5,880,000,000,000

           Scientific notation is 5.88 x 1012 miles.

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Scientific notation is 5 x 10-8 mm

Computation with very large numbers is made easier with scientific notation.

Learning to Use Scientific Notation

When a number is written in scientific notation, the exponent tells you if the term is a large or a small number. A positive exponent indicates a large number and a negative exponent indicates a small number that is between 0 and 1.

Since it’s so useful, let’s look more closely at the details of scientific notation format.

Scientific Notation

A positive number is written in scientific notation if it is written as a x 10n where the coefficient a has a value such that 1 ≤ a < 10 and n is an integer.

Look at the numbers below. Which of the numbers is written in scientific notation?

Number

Scientific Notation?

Explanation

1.85 x 10-2

yes

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-2 is an integer

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no

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Which number below is written in scientific notation?

A) 4.25 x 100.08

B) 0.425 x 107

C) 42.5 x 105

D) 4.25 x 106

Show/Hide Answer

Writing Decimal Notation in Scientific Notation

Now let’s compare some numbers expressed in both scientific notation and standard decimal notation in order to understand how to convert from one form to the other. Take a look at the tables below. Pay close attention to the exponent in the scientific notation and the position of the decimal point in the decimal notation.

Large Numbers

Small Numbers

Decimal Notation

Scientific Notation

Decimal Notation

Scientific Notation

500.0

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0.05

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8 x 104

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6.25 x 1010

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Let’s look at an example.

180,000. =      18,000.0  x  101

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                                                                180.000 x 103

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Notice that the decimal point was moved 5 places to the left, and the exponent is 5.

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A) 7 x 109

B) 0.68 x 1010

C) 6.8 x 109

D) 68 x 108

Show/Hide Answer

Advanced Question

Represent 1.00357 x 10-6 in decimal form.

A) 1.00357000000

B) 0.000100357

C) 0.000001357

D) 0.00000100357

Show/Hide Answer

To write a small number (between 0 and 1) in scientific notation, you move the decimal to the right and the exponent will have to be negative.

                             0.00004     =        00.0004   x  10-1

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