Imagine a chemist is in the lab and trying to make some chemical reactions happen. In one reaction she reacts chemicals in an exothermic reaction and there is an increase in entropy. A second chemical reaction she is trying to run is endothermic and there is a decrease in entropy. Which of the two reactions is more likely to occur and why?
True because it doesn’t count as a full number
Answer:
a) pH = 4.213
b) % dis = 2 %
Explanation:
Ch3COONa → CH3COO- + Na+
CH3COOH ↔ CH3COO- + H3O+
∴ Ka = 1.8 E-5 = ([ CH3COO- ] * [ H3O+ ]) / [ CH3COOH ]
mass balance:
⇒ <em>C</em> CH3COOH + <em>C</em> CH3COONa = [ CH3COOH ] + [ CH3COO- ]
<em>∴ C </em>CH3COOH = 3.40 mM = 3.4 mmol/mL * ( mol/1000mmol)*(1000mL/L)
∴ <em>C</em> CH3COONa = 1.00 M = 1.00 mol/L = 1.00 mmol/mL
⇒ [ CH3COOH ] = 4.4 - [ CH3COO- ]
charge balance:
⇒ [ H3O+ ] + [ Na+ ] = [ CH3COO- ] + [ OH- ]....is negligible [ OH-], comes from water
⇒ [ CH3COO- ] = [ H3O+ ] + 1.00
⇒ Ka = (( [ H3O+ ] + 1 )* [ H3O+ ]) / ( 3.4 - [ H3O+])) = 1.8 E-5
⇒ [ H3O+ ]² + [ H3O+ ] = 6.12 E-5 - 1.8 E-5 [ H3O+ ]
⇒ [ H3O+ ]² + [ H3O+ ] - 6.12 E-5 = 0
⇒ [ H3O+ ] = 6.12 E-5 M
⇒ pH = - Log [ H3O+ ] = 4.213
b) (% dis)* mol acid = <em>C</em> CH3COOH = 3.4
∴ mol CH3COOH = 500*3.4 = 1700 mmol = 1.7 mol
⇒ % dis = 3.4 / 1.7 = 2 %
Answer:
When the sun, moon, and Earth are in alignment (at the time of the new or full moon), the solar tide has an additive effect on the lunar tide, creating extra-high high tides, and very low, low tides—both commonly called spring tides.
Resonance, leaving group, carbonyl carbon delta+, and steric effect is the most crucial variables that affect the relative reactivity of a functional group containing a carbonyl in an addition or substitution process.
Discussion:
1. Carbonyl Carbon Delta+: The carbonyl group becomes more electrophilic and accelerates nucleophilic assault when the carbonyl carbon delta+ is bigger.
2. Resonance: When the carbonyl is transformed into the tetrahedral adduct, it may be lost. Loss of resonance increases the energy of the transition state for this nucleophilic assault because resonance has the function of stabilizing. Therefore, a carbonyl functional group's resistance to nucleophilic attack increases as resonance in the group increases in importance.
3. Leaving group: Tetrahedral adduct fragmentation is encouraged by a better LG.
4. Steric effects: The nucleophilic attack on carbonyl carbon is delayed when sterically impeded.
Learn more about carbonyl here:
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