Answer:
see explanation
Explanation:
Write the balanced COMPLETE ionic equation for the reaction when Na₂CO₃ and AgNO₃ are mixed in aqueous solution. If no reaction occurs, simply write only NR.
Ag (+1) + NO3(-1) + 2 Na(+1) + Co3 (-2)--> Ag2CO3 (s) + 2 Na (+1) + 2NO3(-1)
As we have the balanced reaction equation is:
N2O4 (g) ↔ 2NO2(g)
from this balanced equation, we can get the equilibrium constant expression
KC = [NO2]^2[N2O4]^1
from this expression, we can see that [NO2 ] is with 2 exponent of the stoichiometric and we can see that from the balanced equation as NO2
is 2NO2 in the balanced equation.
and [N2O4] is with 1 exponent of the stoichiometric and we can see that from the balanced equation as N2O4 is 1 N2O4 in the balanced equation.
∴ the correct exponent for N2O4 in the equilibrium constant expression is 1
According to the PH formula:
PH= Pka +㏒ [strong base/weak acid]
when we have PH at the first equivalence =3.35 and the Pka1 = 1.4
So, by substitution, we can get the value of ㏒[strong base / weak acid]
3.35 = 1.4 + ㏒[strong base/ weak acid]
∴㏒[strong base/weak acid] = 3.35-1.4 = 1.95
to get the Pka2 we will substitute with the value of ㏒[strong base/ weak acid] and the value of PH of the second equivalence point
∴Pk2 = PH2 - ㏒[strong base/ weak acid]
= 7.55 - 1.95 = 5.6