Element is a pure substance which is composed of atoms of similar elements.It can not be decomposed into simpler constituents using chemical reactions.Example: Copper
Compound is a pure substance which is made from atoms of different elements combined together in a fixed ratio by mass.It can be decomposed into simpler constituents using chemical reactions. Example: water
Thus as it give that the red sample on being heated, a gas is released and a blue powder is left after the heating. Thus the given sample is a compound.
Susana's red crystal sample is a compound because it was broken down into a gas and blue powder. It is not an element because elements cannot be broken down into simpler substances by ordinary means, such as heating.
An acid rain is an example of a secondary pollutant because it is a chemical reaction of two gases namely, the sulfur dioxide and the nitrogen dioxide. The acid rain is not also directly emitted by the atmosphere.