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Aloiza [94]
3 years ago
9

What is the expected value for the heat of sublimation of acetic acid if its heat of fusion is 10.8 kJ/mol and its heat of vapor

ization is 24.3 kJ/mol
Chemistry
1 answer:
Dennis_Churaev [7]3 years ago
5 0

Answer:

35.1 kJ/mol is the expected value for the heat of sublimation of acetic acid.

Explanation:

CH_3COOH(l)\rightarrow CH_3COOH(g)..[1]

Heat of vaporization of acetic acid = H^o_{vap}=24.3 kJ/mol

CH_3COOH(s)\rightarrow CH_3COOH(l)..[2]

Heat of fusion of acetic acid = H^o_{fus}=10.8 kJ/mol

Heat of sublimation of acetic acid = H^o_{sub}=?

CH_3COOH(s)\rightarrow CH_3COOH(g)..[3]

[1] + [2] = [3] (Hess's law)

H^o_{sub}=H^o_{vap}+H^o_{fus}

=24.3 kJ/mol+10.8 kJ/mol=35.1 kJ/mol

35.1 kJ/mol is the expected value for the heat of sublimation of acetic acid.

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How can you determine which bond in a structure is more polar without using an electronegativity table?
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To know this you pretty much do have to kind of memorize a few electronegativities. I don't recall ever getting a table of electronegativities on an exam.
From the structure, you have:

I remember the following electronegativities most because they are fairly patterned:
EN
H
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EN
C
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N
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O
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Cl
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Δ
EN
C
−
Cl
=
1.0
Δ
EN
C
−
H
=
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Δ
EN
C
−
C
=
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Δ
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C
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O
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Δ
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So naturally, with the greatest electronegativity difference of
4.0
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2.5
=
1.5
, the
C
−
F
bond is most polar, i.e. that bond's electron distribution is the most drawn towards the more electronegative compound as compared to the rest.
When the electron distribution is polarized and drawn towards a more electronegative atom, the less electronegative atom has to move inwards because its nucleus was previously favorably attracted to the electrons from the other atom.
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r
C
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≈
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C
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C
−
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≈
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r
C
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C
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