According to zeroth law of thermodynamics, when two objects are kept in contact, heat (energy) is transferred from one to the other until they reach the same temperature (are in thermal equilibrium). When the objects are at the same temperature there is no heat transfer.
So, at equilibrium,
=
,
+ 
q=m×c×T, where q = heat energy, m = mass of a substance, c = specific heat (units J/kg∙K), T is temperature
=(15X13X4.19)+(148X88.3X4.19)
= 81.37 ° C
Statement that when two elements combine with each other to from more than one compound, the weights of one element that combine with a fixed weight of the other are in a ratio of small whole numbers.
Problem One
You will use both m * c * deltaT and H = m * heat of fusion.
Givens
m = 12.4 grams
c = 0.1291
t1 = 26oC
t2 = 1204
heat of fusion (H_f) = 63.5 J/grams.
Equation
H = m * c * deltaT + m * H_f
Solution
H = 12.4 * 0.1291 * (1063 - 26) + 12.4 * 63.5
H = 1660.1 + 787.4
H = 2447.5 or 2447.47 is the exact answer. I have to leave the rounding to you. I have no idea where to round it although I suspect 2450 would be right for 3 sig digs.
Problem Two
Formula and Givens
t1 = 14.5
t2 = 50.0
E = 5680
c = 4.186
m = ??
E = m c * deltaT
Solution
5680 = m * 4.186 * (50 - 14.5)
5680 = m * 4.186 * (35.5)
5680 = m * 148.603 * m
m = 5680 / 148.603
m = 38.22 grams That isn't very much. Be very sure you are working in joules. You'd leave that many grams in the kettle after drying it thoroughly.
m = 38.2 to 3 sig digs.
If a substance is not chemically pure, it is either a heterogeneous mixture or a homogeneous mixture. If its composition is uniform throughout, it is a homogeneous mixture.