10. In what part of the world might you find Mystery Island (note: you will be given full-credit for simply attempting this ques
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<u>Answer:</u> The time taken by the reaction is 84.5 seconds
<u>Explanation:</u>
The equation used to calculate half life for first order kinetics:
where,
= half-life of the reaction = 9.0 s
k = rate constant = ?
Putting values in above equation, we get:
Rate law expression for first order kinetics is given by the equation:
......(1)
where,
k = rate constant =
t = time taken for decay process = 50.7 sec
= initial amount of the reactant = ?
[A] = amount left after decay process = 0.0741 M
Putting values in equation 1, we get:
Now, calculating the time taken by using equation 1:
Putting values in equation 1, we get:
Hence, the time taken by the reaction is 84.5 seconds
Answer:
1. pH = 1.23.
2.
Explanation:
Hello!
1. In this case, for the ionization of H2C2O4, we can write:
It means, that if it is forming a buffer solution with its conjugate base in the form of KHC2O4, we can compute the pH based on the Henderson-Hasselbach equation:
Whereas the pKa is:
The concentration of the base is 0.347 M and the concentration of the acid is 0.347 M as well, as seen on the statement; thus, the pH is:
2. Now, since the addition of KOH directly consumes 0.070 moles of acid, we can compute the remaining moles as follows:
It means that the acid remains in excess yet more base is yielded due to the effect of the OH ions provided by the KOH; therefore, the undergone chemical reaction is:
Which is also shown in net ionic notation.
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