Answer:
The system makes the transition from nonspontaneous to spontaneous at a temperature of 954.7 K.
Under 954.7 K the reaction is nonspontaneous; more than 954.7 K is the reaction spontaneous.
Explanation:
CH4(g) + 2H2O(g) ⇆ CO2(g) + 4H2(g)
CH4(g) H2O(g) CO2(g) H2(g) ΔH°f (kJ/mol): –74.87 –241.8 –393.5 0
ΔG°f (kJ/mol): –50.81 –228.6 –394.4 0
S°(J/K·mol): 186.1 188.8 213.7 130.7
ΔG<0 to be spontaneous
ΔG = ΔH- TΔS <0
ΔH = ∑nΔH(products) - ∑nΔH(reactant)
ΔH = (-393.5) - (–74.87 + 2*–241.8)
ΔH = 164.97 kJ = 164970 J
ΔS = ∑nΔS(products) - ∑nΔS(reactant)
ΔS = (213.7 + 4*130.7) - (186.1 + 2*188.8)
ΔS = 172.8 J
0 > 164970 J - T* 172.8 J
-164970 J > - T* 172.8 J
954.7< T
The system makes the transition from nonspontaneous to spontaneous at a temperature of 954.7 K.
Under 954.7 K the reaction is nonspontaneous; more than 954.7 K is the reaction spontaneous.
Quantitative data because it involves a number (quantity)
The mechanics of a power plant that generally uses nuclear energy in order to generate electricity lies in the principle of nuclear fission between radioactive atoms. In addition, among its major arguments on why it is still a matter of ethical issue is because of the intensive maintenance it requires for the disposal of its radioactive wastes.
Answer:
1 kilogram weight at sea level would be the equivalent of 2 pounds.
Explanation:
<u>Answer:</u> The pH of the buffer is 4.61
<u>Explanation:</u>
To calculate the pH of acidic buffer, we use the equation given by Henderson Hasselbalch:
![pH=pK_a+\log(\frac{[\text{conjuagate base}]}{[\text{acid}]})](https://tex.z-dn.net/?f=pH%3DpK_a%2B%5Clog%28%5Cfrac%7B%5B%5Ctext%7Bconjuagate%20base%7D%5D%7D%7B%5B%5Ctext%7Bacid%7D%5D%7D%29)
We are given:
= negative logarithm of acid dissociation constant of weak acid = 4.70
![[\text{conjuagate base}]}](https://tex.z-dn.net/?f=%5B%5Ctext%7Bconjuagate%20base%7D%5D%7D)
= moles of conjugate base = 3.25 moles
![[\text{acid}]](https://tex.z-dn.net/?f=%5B%5Ctext%7Bacid%7D%5D)
= Moles of acid = 4.00 moles
pH = ?
Putting values in above equation, we get:
Hence, the pH of the buffer is 4.61
