Answer:
E = 0.062 V
Explanation:
(a) See the attached file for the answer
(b)
Calculating the voltage (E) using the formula;
E = - (2.303RT/nf)log Cathode/Anode
Where,
R = 8.314 J/K/mol
T = 35°C = 308 K
F- Faraday's constant = 96500 C/mol,
n = number of moles of electron = 2
Substituting, we have
E = -(2.303 * 8.314 *308/2*96500) *log (0.03/3)
= -0.031 * -2
= 0.062V
Therefore, the voltmeter will show a voltage of 0.062 V
<u>Answer:</u> The concentration of unknown phosphoric acid solution is 0.034 M
<u>Explanation:</u>
To calculate the concentration of acid, we use the equation given by neutralization reaction:
where,
are the n-factor, molarity and volume of acid which is
are the n-factor, molarity and volume of base which is NaOH.
We are given:
Putting values in above equation, we get:
Hence, the concentration of unknown phosphoric acid solution is 0.034 M