When you bring two objects of different temperature together, energy will always be transferred from the hotter to the cooler object. The objects will exchange thermal energy, until thermal equilibrium is reached, i.e. until their temperatures are equal. We say that heat flows from the hotter to the cooler object. Heat is energy on the move.
Units of heat are units of energy. The SI unit of energy is Joule. Other often encountered units of energy are 1 Cal = 1 kcal = 4186 J, 1 cal = 4.186 J, 1 Btu = 1054 J.
Without an external agent doing work, heat will always flow from a hotter to a cooler object. Two objects of different temperature always interact. There are three different ways for heat to flow from one object to another. They are conduction, convection, and radiation.
Most reactions are exothemic. If the forward reaction of an equilibrium reaction is exothemic then the reverse reaction must be endothermic.
If a system in equilibrium is heated, it will move in exothermic direction to give out heat energy.
Choice-a is a very rubbery, imprecise, ambiguous, slippery statement. But it's probably less wrong than any of the other choices on the list.