All water is located in this layer

Draw the products formed when cholesterol is treated with [1] bh3·thf; [2] h2o2, −oh. indicate the stereochemistry around any st

Andreas93 [3]

Alkene on Hydration yield Alcohols. When Asymmetric Alkenes are treated with water in the presence of acid they follow Markovnikoff rule, and the Hydrogen of incoming reagent goes to that carbon which contain more number of Hydrogen atoms. The reverse (Anti-Markovnikoff) is done by carrying out Hydroboration reaction.In this case the Hydrogen atom of incoming reagent goes to that carbon which contains less number of Hydrogen atoms. In this reaction both -H and -OH adds in syn fashion. The Hydroboration reaction of Chloestrol is shown below,

3 0

3 years ago

Many power plants produce energy by burning carbon-based fuels, which also produces carbon dioxide. Carbon dioxide is a greenhou

RUDIKE [14]

Answer:

a) 2.541 mol/MJ;

b) 1.124 mol/MJ;

c) 0.4354 mol/MJ;

d) 0.1835 mol/MJ

Explanation:

The enthalpy of formation (ΔH°f) is the enthalpy of a reaction to form a compound by its constituents. For CO₂, ΔH°f = - 393.5 kJ/mol.

The enthalpy of a reaction is the sum of the enthalpy of the products (each one multiplied by the number of moles) less the sum of the enthalpy of the reactants (each one multiplied by the number of moles). The ΔH°f for simple substances (with one atom) is 0. The combustion is the reaction between the fuel and the oxygen.

a) The combution reaction is:

C(s) + O₂(g) → CO₂(g)

ΔH°rxn = -393.5 kJ/mol = -393.5x10⁻³ MJ/mol

Number of moles per MJ released: 1/|ΔH°rxn|

n = 1/(393.5x10⁻³) = 2.541 mol/MJ

b) The combustion reaction is:

CH₄(g) + 2O₂(g) → CO₂(g) + 2H₂O(l)

H₂O is in the liquid state because it's at 1 atm and 25ºC.

ΔH°f, H₂O(l) = -285.3 kJ/mol

ΔH°f, O₂(g) = 0

ΔH°f, CH₄(g) = -74.8 kJ/mol

ΔH°rxn = [2*(-285.3 ) + 1*(-393.5)] - [1*(-74.8)]

ΔH°rxn = -889.3 kJ/mol = -889.3x10⁻³ MJ/mol

n = 1/889.3x10⁻³ = 1.124 mol/MJ

c) C₃H₈(g) + 10O₂(g) → 3CO₂(g) + 4H₂O(l)

ΔH°f,C₃H₈(g) = -25.2 kJ/mol

ΔH°rxn = [4*(-285.3) + 3*(-393.5)] - [1*(-25.2)]

ΔH°rxn = -2,296.5 kJ/mol = -2.2965 MJ/mol

n = 1/2.2965 = 0.4354 mol/MJ

d) C₈H₁₈(l) + (25/2)O₂(g) → 8CO₂(g) + 9H₂O(l)

ΔH°f, C₈H₁₈(l) = -250.1 kJ/mol

ΔH°rxn = [9*(-283.5) + 8*(-393.5)] - [1*(-250.1)]

ΔH°rxn = -5,449.4 kJ/mol = -5.4494 MJ/mol

n = 1/5.4494 = 0.1835 mol/MJ

4 0

3 years ago

A solution was prepared by dissolving 0.800 g of sulfur S8, in 100.0 g of acetic acid, HC2H3O2. Calculate the freezing point and

sammy [17]

Answer: The freezing point of solution is 16.5°C and the boiling point of solution is 118.2°C

Explanation:

To calculate the molality of solution, we use the equation:

$Molality=\frac{m_{solute}\times 1000}{M_{solute}\times W_{solvent}\text{ in grams}}$

Where,

$m_{solute}$ = Given mass of solute $(S_8)$ = 0.800 g

$M_{solute}$ = Molar mass of solute $(S-8)$ = 256.52 g/mol

$W_{solvent}$ = Mass of solvent (acetic acid) = 100.0 g

Putting values in above equation, we get:

$\text{Molality of solution}=\frac{0.800\times 1000}{256.52\times 100.0}\\\\\text{Molality of solution}=0.0312m$

Calculation for freezing point of solution:

Depression in freezing point is defined as the difference in the freezing point of water and freezing point of solution.

$\Delta T_f=\text{freezing point of acetic acid}-\text{Freezing point of solution}$

To calculate the depression in freezing point, we use the equation:

$\Delta T_f=iK_fm$

or,

$\text{Freezing point of acetic acid}-\text{Freezing point of solution}=iK_fm$

where,

Freezing point of acetic acid = 16.6°C

i = Vant hoff factor = 1 (for non-electrolyte)

$K_f$ = molal freezing point depression constant = 3.59°C/m

m = molality of solution = 0.0312 m

Putting values in above equation, we get:

$16.6^oC-\text{freezing point of solution}=1\times 3.59^oC/m\times 0.0312m\\\\\text{Freezing point of solution}=16.5^oC$

Hence, the freezing point of solution is 16.5°C

Calculation for boiling point of solution:

Elevation in boiling point is defined as the difference in the boiling point of solution and freezing point of pure solution.

The equation used to calculate elevation in boiling point follows:

$\Delta T_b=\text{Boiling point of solution}-\text{Boiling point of acetic acid}$

To calculate the elevation in boiling point, we use the equation:

$\Delta T_b=iK_bm$

or,

$\text{Boiling point of solution}-\text{Boiling point of acetic acid}=iK_fm$

where,

Boiling point of acetic acid = 118.1°C

i = Vant hoff factor = 1 (for non-electrolyte)

$K_f$ = molal boiling point elevation constant = 3.08°C/m

m = molality of solution = 0.0312 m

Putting values in above equation, we get:

$\text{Boiling point of solution}-118.1^oC=1\times 3.08^oC/m\times 0.0312m\\\\\text{Boiling point of solution}=118.2^oC$

Hence, the boiling point of solution is 118.2°C

5 0

3 years ago

Say something hot ;)

Fed [463]

sometimes I think of plss, and it reminds me of you *bites lip*

5 0

2 years ago

Read 2 more answers

How many mL of a 0.250M sodium hydroxide solution is needed to neutralize 25.0 mL of a 0.430M sulfuric acid solution?

kotykmax [81]

Answer:

86.0 mL

Explanation:

i just did the USA test prep

5 0

3 years ago