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Shtirlitz [24]
3 years ago
9

Write a balanced net ionic equation for the following reaction. Explain how you arrived at this answer. What did you cancel out?

Chemistry
1 answer:
Alex787 [66]3 years ago
4 0

 The net ionic equation  is

Ag⁺(aq)  +Cl⁻(aq) →  AgCl(s)

<u><em>Explanation</em></u>

AgNO₃ (aq)  + KCl (aq)→ AgCl(s) +KNO₃(aq)


from above  molecular equation break  all  soluble electrolyte  into ions

Ag⁺(aq) +NO₃⁻ (aq) + K⁺(aq) +Cl⁻(aq) →   AgCl (s) + K⁺(aq) + No₃⁻(aq)


cancel the spectator  ions  in both side  of  equation =K⁺  and NO₃⁻  ions


The net  ionic equation is therefore

= Ag⁺(aq)  + Cl⁻(aq) →    AgCl(s)

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Consider the following reaction between mercury(II) chloride and oxalate ion.
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<u>Answer:</u> The rate law of the reaction is \text{Rate}=k[HgCl_2][C_2O_4^{2-}]^2

<u>Explanation:</u>

Rate law is defined as the expression which expresses the rate of the reaction in terms of molar concentration of the reactants with each term raised to the power their stoichiometric coefficient of that reactant in the balanced chemical equation.

For the given chemical equation:

2 HgCl_2(aq.)+C_2O_4^{2-}(aq.)\rightarrow 2Cl^-(aq.)+2CO_2(g)+Hg_2Cl_2(s)

Rate law expression for the reaction:

\text{Rate}=k[HgCl_2]^a[C_2O_4^{2-}]^b

where,

a = order with respect to HgCl_2

b = order with respect to C_2O_4^{2-}

Expression for rate law for first observation:

3.2\times 10^{-5}=k(0.164)^a(0.15)^b  ....(1)

Expression for rate law for second observation:

2.9\times 10^{-4}=k(0.164)^a(0.45)^b  ....(2)

Expression for rate law for third observation:

1.4\times 10^{-4}=k(0.082)^a(0.45)^b  ....(3)

Expression for rate law for fourth observation:

4.8\times 10^{-5}=k(0.246)^a(0.15)^b  ....(4)  

Dividing 2 from 1, we get:

\frac{2.9\times 10^{-4}}{3.2\times 10^{-5}}=\frac{(0.164)^a(0.45)^b}{(0.164)^a(0.15)^b}\\\\9=3^b\\b=2

Dividing 2 from 3, we get:

\frac{2.9\times 10^{-4}}{1.4\times 10^{-4}}=\frac{(0.164)^a(0.45)^b}{(0.082)^a(0.45)^b}\\\\2=2^a\\a=1

Thus, the rate law becomes:

\text{Rate}=k[HgCl_2]^1[C_2O_4^{2-}]^2

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The slightly negative oxygen end of water molecule gets near the Na+, while the slightly positive Hydrogen of water molecule gets near the Cl-.

So before salt sample dissolve, the water molecules were highly ordered due to hydrogen bonding. Now after salt dissolve there is a decrease in order and thus an increase in disorder of the water molecules.

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