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FinnZ [79.3K]
3 years ago
12

The electron pair geometry of a molecule is tetrahedral. What is its bond angle if it shows one lone pair of electrons and three

bonding pairs?
A) Less than 109.5°
B) More than 109.5°
C) Equal to 109.5°
D) Zero

Chemistry
2 answers:
den301095 [7]3 years ago
3 0
I think is Gonna be C
murzikaleks [220]3 years ago
3 0

Answer:  A) Less than 109.5°

Explanation: The electron pair geometry of a molecule is tetrahedral , which means the number of electrons is 4 that means the hybridization will be sp^3. and the bond angle will be 109.5°.

But as one lone pair of electrons and three bonding pairs are present, the fourth position will be occupied by lone pair of electrons. The repulsion between lone and bond pair of electrons is more and hence the bond angle will decrease from 109.5° and molecular geometry will be trigonal pyramidal.

As in ammonia molecule, the bond angle reduces to 107° due to the presence of lone pair of electron in tetrahedral geometry.

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What mass of solid that has a molar mass 89.0 g/mol should be added to 100.0 g of benzene to raise the boiling point of benzene
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On the basis of given data:

Mass of solvent (benzene) = 100 gm or 0.1 Kg

Molar mass of solute (solid) = 89 g/mol

Increase in boiling point (deltaTb) = 2.42 degree C

The boiling point elevation constant k = 2.53 C.kg/mol

There is a need to determine the mass of the solid to be added, the elevation in boiling point is proportional to the m (molality) of the solute;

ΔTb = k.m

Here, m that is molality = moles of solute/kg of solvent

Therefore,

ΔTb = k (benzene) × moles of solid/kg of benzene

2.42 = 2.53 × moles of solid/0.1

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The equilibrium constant Kp for the reaction (CH3),CCI (g) = (CH3),C=CH, (g) + HCl (g) is 3.45 at 500. K. (5.00 x 10K) Calculate
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<u>Answer:</u> The value of K_p for the reaction is 6.32 and concentrations of (CH_3)_2C=CH,HCl\text{ and }(CH_3)_3CCl is 0.094 M, 0.094 M and 0.106 M respectively.

<u>Explanation:</u>

Relation of K_p with K_c is given by the formula:

K_p=K_c(RT)^{\Delta ng}

where,

K_p = equilibrium constant in terms of partial pressure = 3.45

K_c = equilibrium constant in terms of concentration = ?

R = Gas constant = 0.0821\text{ L atm }mol^{-1}K^{-1}

T = temperature = 500 K

\Delta n_g = change in number of moles of gas particles = n_{products}-n_{reactants}=2-1=1

Putting values in above equation, we get:

3.45=K_c\times (0.0821\times 500)^{1}\\\\K_c=\frac{3.45}{0.0821\times 500}=0.084

The equation used to calculate concentration of a solution is:

\text{Molarity}=\frac{\text{Moles}}{\text{Volume (in L)}}

Initial moles of (CH_3)_3CCl(g) = 1.00 mol

Volume of the flask = 5.00 L

So, \text{Concentration of }(CH_3)_3CCl=\frac{1.00mol}{5.00L}=0.2M

For the given chemical reaction:

                (CH_3)_3CCl(g)\rightarrow (CH_3)_2C=CH(g)+HCl(g)

Initial:               0.2                    -                        -

At Eqllm:          0.2 - x               x                       x

The expression of K_c for above reaction follows:

K_c=\frac{[(CH_3)_2C=CH]\times [HCl]}{[(CH_3)_3CCl]}

Putting values in above equation, we get:

0.084=\frac{x\times x}{0.2-x}\\\\x^2+0.084x-0.0168=0\\\\x=0.094,-0.178

Negative value of 'x' is neglected because initial concentration cannot be more than the given concentration

Calculating the concentration of reactants and products:

[(CH_3)_2C=CH]=x=0.094M

[HCl]=x=0.094M

[(CH_3)_3CCl]=(0.2-x)=(0.2-0.094)=0.106M

Hence, the value of K_p for the reaction is 6.32 and concentrations of (CH_3)_2C=CH,HCl\text{ and }(CH_3)_3CCl is 0.094 M, 0.094 M and 0.106 M respectively.

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