Determine if each statement below is True or False regarding Arrhenius and Br∅nsted-Lowry definitions for acids and bases.
1 answer:
Answer:
All statements are true
Explanation:
Arrhenius theory:-
The Arrhenius theory was introduced introduced by Swedish scientist named Svante Arrhenius in 1887.
According to the theory, acids are the substances which dissociate in the aqueous medium to produce electrically charged atoms ( may be molecule). Out of these species furnished, one must be a proton or the hydrogen ion, .
Hence, statement 1 is correct.
Bronsted-Lowry base is the specie which accepts the proton form the medium. For example, Benzoate ion is the conjugate base of the benzoic acid. It is a Bronsted-Lowry base and the dissociation of benzoate ion can be shown as:-
Hence, statement 2 is correct.
Acetic acid will dissociate as:-
Hence, statement 3 is also correct.
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Answer: -
12.59
Explanation: -
Strength of NaOH = 0.0179 M
Volume of NaOH = 58.0 mL = 58.0/1000 = 0.058 L
Number of moles = 0.0179 M x 0.058 L
= 1.04 x 10⁻³ mol
Mol of [OH⁻] given by NaOH = 1.04 x 10⁻³ mol
Strength of Ba(OH)₂ = 0.0294 M
Volume of Ba(OH)₂ = 60.0 mL = 60.0/1000 = 0.060 L
Number of moles = 0.0294 M x 0.060 L
= 1.76 x 10⁻³ mol
Mol of [OH⁻] given by Ba(OH)₂ =2 x 1.76 x 10⁻³ mol
Total [OH⁻] = 1.04 x 10⁻³ mol + 2 x 1.76 x 10⁻³ mol
= 4.56 x 10⁻³ mol
Total volume of the mixture = 58.0 + 60.0
= 118.0 mL
118.0 mL of the solution has 4.56 x 10⁻³ mol [OH⁻]
1000 mL of the solution has
= 0.0386 mol
Using the relation
pOH = - log [OH-]
= - log 0.0386
= 1.41
Using the relation
pH + pOH = 14
pH = 14 - 1.41
= 12.59