Answer:
The equilibrium constant for the reversible reaction = 0.0164
Explanation:
At equilibrium the rate of forward reaction is equal to the rate of backwards reaction.
The reaction is given as
A ⇌ B
Rate of forward reaction is first order in [A] and the rate of backward reaction is also first order in [B]
The rate of forward reaction = |r₁| = k₁ [A]
The rate of backward reaction = |r₂| = k₂ [B]
(Taking only the magnitudes)
where k₁ and k₂ are the forward and backward rate constants respectively.
k₁ = 0.010 s⁻¹
k₂ = 0.0610 s⁻¹
|r₁| = 0.010 [A]
|r₂| = 0.016 [B]
At equilibrium, the rate of forward and backward reactions are equal
|r₁| = |r₂|
k₁ [A] = k₂ [B] (eqn 1)
Note that equilibrium constant, K, is given as
K = [B]/[A]
So, from eqn 1
k₁ [A] = k₂ [B]
[B]/[A] = (k₁/k₂) = (0.01/0.0610) = 0.0163934426 = 0.0164
K = [B]/[A] = (k₁/k₂) = 0.0164
Hope this Helps!!!
0.300 M IKI represents the
concentration which is in molarity of a potassium iodide solution. This means
that for every liter of solution there are 0.300 moles of potassium iodide. Knowing
that molarity is a ratio of solute to solution.
By using a conversion factor:
100 ml x (1L / 1000 mL) x (0.300
mol Kl / 1 L) x (166.0g / 1 mol Kl) = 4.98 g
Therefore, in the first
conversion by simply converting the unit of volume to liter, Molarity is in L
where the volume is in liters. The next step is converted in moles from volume
by using molarity as a conversion factor which is similar to how density can be
used to convert between volume and mass. After converting to moles it is simply
used as molar mass of Kl which is obtained from periodic table to convert from
mole to grams.
In order to get the grams of IKI
to create a 100 mL solution of 0.600 M IKI, use the same formula as above:
100 ml x (1L / 1000 mL) x (0.600
mol Kl / 1 L) x (166.0g / 1 mol Kl) = 9.96 g
Answer: The value of 
for the half-cell reaction is 0.222 V.
Explanation:
Equation for solubility equilibrium is as follows.
Its solubility product will be as follows.
![K_{sp} = [Ag^{+}][Cl^{-}]](https://tex.z-dn.net/?f=K_%7Bsp%7D%20%3D%20%5BAg%5E%7B%2B%7D%5D%5BCl%5E%7B-%7D%5D)
Cell reaction for this equation is as follows.
Reduction half-reaction: 
, 
Oxidation half-reaction: 
, 
= ?
Cell reaction: 
So, for this cell reaction the number of moles of electrons transferred are n = 1.
Solubility product,
= 
Therefore, according to the Nernst equation
![E_{cell} = E^{o}_{cell} - \frac{0.0592 V}{n} log \frac{[AgCl]}{[Ag^{+}][Cl^{-}]}](https://tex.z-dn.net/?f=E_%7Bcell%7D%20%3D%20E%5E%7Bo%7D_%7Bcell%7D%20-%20%5Cfrac%7B0.0592%20V%7D%7Bn%7D%20log%20%5Cfrac%7B%5BAgCl%5D%7D%7B%5BAg%5E%7B%2B%7D%5D%5BCl%5E%7B-%7D%5D%7D)
At equilibrium, 
= 0.00 V
Putting the given values into the above formula as follows.
![0.00 = E^{o}_{cell} - \frac{0.0592 V}{1} log \frac{1}{[Ag^{+}][Cl^{-}]}](https://tex.z-dn.net/?f=0.00%20%3D%20E%5E%7Bo%7D_%7Bcell%7D%20-%20%5Cfrac%7B0.0592%20V%7D%7B1%7D%20log%20%5Cfrac%7B1%7D%7B%5BAg%5E%7B%2B%7D%5D%5BCl%5E%7B-%7D%5D%7D)
= 
= 0.577 V
Hence, we will calculate the standard cell potential as follows.
= 0.222 V
Thus, we can conclude that value of for the half-cell reaction is 0.222 V.
I believe it is less dense.. that is why ice floats on water
